372(1-2) (2000), 85-93
Sulfonatcd C-60, 5,10,15,20-tetra kis 4-[meso-tetra-methyl (4- pyridinyl)] porphyrin (C-60(SO3-)(n)-TMePyP4+) complex films have been prepared by electrostatic self-assembly of each chromophore from solution. When these complex films are formed on a thin film of chitosan polymer, the stacked bilayer films exhibit nearly twice the absorption as those prepared on conventional silanized substrates. X-ray photoelectron spectroscopy measurements disclose a strong interaction between the C-60(SO3-)(n) and TMePyP4+. Atomic force microscopy results of the surface morphology, hardness, and the chemical functionality are used to explain the differences between substrate treatments. (C) 2000 Elsevier Science S.A. All rights reserved.
[166] Effect of Added Ionic Salt on the Quantum Efficiency of Self- Assembled Films Prepared with Poly( P-Phenylene Vinylene)
J. Cho, K. Char, S. Y. Kim, J. D. Hong, S. K. Lee and D. Y. Kim
Thin Solid Films
Dostları ilə paylaş: |