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Subject: ORGLIST: New Video lecture by Ian Fleming



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Subject: ORGLIST: New Video lecture by Ian Fleming
We are delighted to announce a new chemistry video lecture, by Ian

Fleming from the University of Cambridge, on


"Stereo Control in Organic Synthesis using Silicon Compounds"
Its at http://www.ch.ic.ac.uk/video/
(or directly at http://www.ch.ic.ac.uk/video/fleming/ )
We also introduce the use of SVG graphics, to allow the best possible

resolution for the lecture slides. You will need an SVG plugin

(and eg Chime/Chem3D) to take full advantage of the lecture.
We will also shortly introduce a SMIL (Synchronised Multimedia Integration Langauge)

version, once one particularly difficult bug is resolved.

--
Henry Rzepa. +44 (0)20 7594 5774 (Office) +44 (0)20 7594 5804 (Fax)

Dept. Chemistry, Imperial College, London, SW7 2AY, UK.

http://www.ch.ic.ac.uk/rzepa/

__________________



Date: Wed, 15 Mar 2000 00:50:46 -0500

From: Merlin

Subject: ORGLIST: Press Conference on Human Genome Project, 3.15.00
Anyone else watch the Press Conference today?
Comments, questions?
--

George D. 'Merlin' McCallion, Research Chemist

Department of Anesthesiology

The Children's Hospital of Philadelphia

Post Office Box 143

Bala-Cynwyd, PA 19004-0143


Office: 1.215.590.6894

Fax: 1.215.590.4554

Email: medchem@home.com
__________________

Date: Wed, 15 Mar 2000 15:17:11 -0800 (PST)

From: Luis Manuel Armas

Subject: ORGLIST: jasmonic acid and relates products.
Dears friends:
Please, I am interested to get any information about

companies or laboratories that made jasmonic acid or

another related product of jasmonic acid, and how can

get this chemical.


My best wishes
Luis Manuel Armas

Facultadad de Quimica,

Universidad de la Habana

Zapatata y G., Vedado

CH10400

Cuba
__________________



Date: Thu, 16 Mar 2000 10:32:32 +0800

From: Jiang Heng

Subject: ORGLIST: oxystearic acid
Who can tell me how to synthesis oxystearic acid. Is there any relevant literature?

Thanks
Jiang Heng

hjiang@fspu.edu.cn
__________________

Date: Thu, 16 Mar 2000 15:4:48 +0800

From: Jiang Heng

Subject: ORGLIST: estolide

Organization: Fushun Petroleum Institute
Who can tell me what is the meaning of the word "estolide"
Jiang Heng

hjiang@fspu.edu.cn


__________________

Date: Thu, 16 Mar 2000 13:44:37 +0100

From: "J.Aires de Sousa"

Subject: Re: ORGLIST: estolide
> Who can tell me what is the meaning of the word "estolide"
Why don’t you try a search engine before sending such a

question to ORGLIST ?

I simply looked for 'estolide' in GOOGLE (www.google.com)

and found several useful links that answer your question (I

will not tell you the answer, anyway! :-)
Joao Aires de Sousa, Ph.D.

e-mail: jas@mail.fct.unl.pt


Departamento de Quimica, Fac. Ciencias e Tecnologia,

Univ. Nova de Lisboa, 2825 - 114 Caparica, Portugal;

__________________

Date: Thu, 16 Mar 00 18:29 EST

From: bgen@csd.univ.ploiesti.ro

Subject: ORGLIST: PE analyses
Hello everybody,

I would be grateful if someone could suggest some literature

references (or would be interested to discuss details) regarding

methods to analyze polyethylene and polypropylene by FTIR and

NMR (such as degree of crystallinity, branching and so on). Thanks,
Eugen Barbu

bgen@gmx.de


__________________

Date: 18 Mar 2000 05:11:22 -0800

From: Juana L

Subject: ORGLIST: methyl cyclohexene from methyl cyclohexanone
Hello

I will like to synthetize methyl cyclohexane from methyl cyclohexanone. I will like to know if it is posible to do in just one step.I would greatly appreciate anyone who can point me to good references on this, because I have searched in some books with no success.

Thank you
Juana L.
__________________

Date: Tue, 18 Apr 2000 01:17:58 -0400

From: Glen Brizius

Subject: ORGLIST: Synthesis Approach
Hello, all. I am trying to synthesize compounds with the following

molecular structure: RBrC(double bond)CBrR, where the halogens are

preferably trans to each other. An example would be

trans-2,3-dibromo-2-butene, which would have pendant methyl groups.

Ideally I'd like to have control over the identity of the alkyl groups,

which would hopefully come from commercially available precursors (alkyl

bromides, alcohols, aldehydes, etc).
So far I've tried transforming trans-2,3-dibromo-1,4-dihydroxy-2-butene

into the 1,2,3,4-tetrabromo-2-butene with PBr3, followed by reaction

with alkyl Grignard reagents. However, this gives me a complex mixture

of (allylic rearranged) products. While I can make the dialkoxy

versions easily, they are not any good for my particular reaction, they

have to be alkyl.


Does anyone have any experience in this type of synthesis that would

like to share? All opinions gratefully :) accepted via email. Thanks

in advance!
Glen Brizius
__________________

Date: Mon, 20 Mar 2000 00:46:26 -0800 (PST)

From: HU HONGKUN

Subject: ORGLIST: help!!!!
hello!Everyone!

I am a graduate in the Colllege of Chemic in the

Sichuan University.

I want someone find me a reference.

Galvanotechnik 1998,89(3),748-749 Eugen G.Leuze

verlag


I can not find it here.It means a lot to me. So

please help me .Thanks a lot!!!!

you can contact me with email!
=====

your sincerely Hu Hongkun


__________________

Date: Mon, 20 Mar 2000 15:19:04 +0100

From: "Yantao Chen"

Subject: ORGLIST: about reduction
Dear Orglist Members:
I just finished the reduction of azido group (R-N3) into amine (R-NH2) using

PPh3 in MeOH. According to the scale of R-N3 I used, more than 11 ml of N2

should be obtained. I used one empty balloon to check how much the gas I

would have, but, to my surprise, the balloon was always empty. However, some

other references introduced the same reductive reagent, but first reacted in

THF then add some water. In these paper, the authors suggest that we can

infer if the reduction completed or not just according to observe if the N2

bubble was stopped. Finally, The yield of this reduction using PPh3/MeOH is

over 80%, while nearly nothing when trying the system of PPh3/THF/H2O. Can

you explain it? Then email me your possible mechanism. Thank you.


Yantao Chen

yanch@ifm.liu.se


__________________

Date: Mon, 20 Mar 2000 15:46:33 +0100

From: "Schuit, ing. R.C."

Subject: ORGLIST: propyphenazone
Can anyone provide me with the structure of propyphenazone. A painkiller.

Can't find anything on the web.


Cheers, Robert

__________________



Date: Mon, 20 Mar 2000 17:06:41 +0100

From: Jonas Nilsson

Subject: Re: ORGLIST: propyphenazone
I would say
www.chemfinder.com
is a good place to start. Beware however. I've spoted several errors in the

database.

/jN
_____________________ _____________________

| Jonas Nilsson | | |

|Linkoping University | | Telephone |

| IFM | | --------- |

| Dept. of Chemistry | | work: +46-13-285690 |

| 581 83 Linkoping | | fax: +46-13-281399 |

| Sweden | | home: +46-13-130294 |

|_____________________| |_____________________|


__________________

Date: Tue, 21 Mar 2000 02:42:24 -0800 (PST)

From: lia kamelia

Subject: ORGLIST: ligand
dear people
can somebody answer my question?
which ligand is stronger, acetilacetone or etilendiamine?
thanks
__________________
Date: Mon, 20 Mar 2000 12:23:30 -0500

From: Herb Hedgecock
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