Marc Andrew Hillmyer



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2015, 5, 19–25.
DOI: 10.1007/s13203-014-0048-z

(300) McIntosh, L. D.; Schulze, M. W.; Irwin, M. T.; Hillmyer, M. A.; Lodge, T. P. – Evolution of Morphology, Modulus, and Conductivity in Polymer Electrolytes Prepared via Polymerization-Induced Phase Separation – Macromolecules 2015, 48, 1418−1428. DOI: 10.1021/ma502281k

(299) Ricarte, R. G.; Lodge, T. P.; Hillmyer, M. A. – Detection of pharmaceutical drug crystallites in solid dispersions by transmission electron microscopy – Mol. Pharmaceutics 2015, 12, 983–990. DOI: 10.1021/mp500682x

(298) Lin, C. -H.; Polisetty, S.; O’Brien, L.; Baruth, A.; Hillmyer, M. A.; Leighton, C.; Gladfelter, W. L. – Size-Tuned ZnO Nanocrucible Arrays for Magnetic Nanodot Synthesis via Atomic Layer Deposition-Assisted Block Polymer Lithography – ACS Nano 2015, 9, 1379–1387. DOI: 10.1021/nn505731n

(297) John, A.; Hogan, L. T.; Hillmyer, M. A.; Tolman, W. B. – Olefins from biomass feedstocks: catalytic ester decarbonylation and tandem Heck-type coupling – Chem. Commun. 2015, 51, 2731–2733.
DOI: 10.1039/C4CC09003A

(296) Seo, M.; Kim, S.; Oh, J.; Kim, S. -J.; Hillmyer, M. A. – Hierarchically Porous Polymers from Hyper-cross-linked Block Polymer Precursors – J. Am. Chem. Soc. 2015, 137, 600–603. DOI: 10.1021/ja511581w

(295) Martinez, H.; Hillmyer, M. A.; Cramer, C. J. – Factors Controlling Selectivity in the Ring-Opening Metathesis Polymerization of 3‐Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts – J. Org. Chem. 2014, 79, 11940−11948. DOI: 10.1021/jo501732q

(294) Seo, M.; Moll, D., Silvis, C.; Roy, A.; Querelle, S.; Hillmyer, M. A. – Interfacial Polymerization of Reactive Block Polymers for the Preparation of Composite Ultrafiltration Membranes
– Ind. Eng. Chem. Res. 2014, 53, 18575−18579. DOI: 10.1021/ie5032259

(293) Martello, M. T.; Schneiderman, D. K.; Hillmyer, M. A. – Synthesis and Melt Processing of Sustainable Poly(ε-decalactone)-block-Poly(lactide) Multiblock Thermoplastic Elastomers – ACS Sustainable Chem. Eng. 2014, 2, 2519−2526. DOI: 10.1021/sc500412a

(292) Neitzel, A. E.; Peteresen, M. A.; Kokkoli, E.; Hillmyer, M. A. – Divergent Mechanistic Avenues to an Aliphatic Polyesteracetal or Polyester from a Single Cyclic Esteracetal – ACS Macro Lett. 2014, 3, 1156–1160.


DOI: 10.1021/mz5005794

(291) Paulsen, B. D.; Speros, J. C.; Clafin, M. S.; Hillmyer, M. A.; Frisbie, C. D. – Tuning of HOMO energy levels and open circuit voltages in solar cells based on statistical copolymers prepared by ADMET polymerization – Polym. Chem. 2014, 5, 6287–6294. DOI: 10.1039/C4PY00832D

(290) Nasiri, M.; Bertrand, A.; Reineke, T. M.; Hillmyer, M. A. – Polymeric Nanocylinders by Combining Block Copolymer Self-Assembly and Nanoskiving – ACS Appl. Mater. Interfaces 2014, 6, 16283−16288.
DOI: 10.1021/am504486r

(289) Baruth, A.; Seo, M.; Lin, C. H.; Walster, K.; Shankar, A.; Hillmyer, M. A.; Leighton, C. – Optimization of Long-Range Order in Solvent Vapor Annealed Poly(styrene)-block-poly(lactide) Thin Films for Nanolithography – ACS Appl. Mater. Interfaces 2014, 6, 13770−13781. DOI: 10.1021/am503199d

(288) Chaffin, K. A.; Chen, X.; McNamara, L.; Bates, F. S.; Hillmyer, M. A. – Polyether Urethane Hydrolytic Stability after Exposure to Deoxygenated Water – Macromolecules 2014, 47, 5220–5226. DOI: 10.1021/ma500904d

(287) Bolton, J. M.; Hillmyer, M. A.; Hoye, T. R. – Sustainable Thermoplastic Elastomers from Terpene-Derived Monomers
– ACS Macro Lett. 2014, 3, 717–720. DOI: 10.1021/mz500339h

(286) Sinturel, C.; Grosso, D.; Boudot, M.; Amenitsch, H.; Hillmyer, M. A.; Pineau, A.; Vayer, M. – Structural Transitions in Asymmetric Poly(styrene)-block-Poly(lactide) Thin Films Induced by Solvent Vapor Exposure – ACS Appl. Mater. Interfaces 2014, 6, 12146–12152. DOI: 10.1021/am504086x

(285) Touris, A.; Chanpuriya, S.; Hillmyer, M. A.; Bates, F. S. – Synthetic strategies for the generation of ABCA' type asymmetric tetrablock terpolymers – Polym. Chem. 2014, 5, 5551–5559. DOI: 10.1039/C4PY00614C

(284) Hillmyer, M. A.; Tolman, W. B. – Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable – Acc. Chem. Res. 2014, 47, 2390–2396. DOI: 10.1021/ar500121d

(283) Brutman, J. P.; Delgado, P. A.; Hillmyer, M. A. – Polylactide Vitrimers – ACS Macro Lett. 2014, 3, 607–610. DOI: 10.1021/mz500269w

(282) Xiong, M.; Schneiderman, D. K.; Bates, F. S.; Hillmyer, M. A.; Zhang, K. – Scalable production of mechanically tunable block polymers from sugar – PNAS 2014, 111, 8357–8362. DOI: 10.1073/pnas.1404596111

(281) Dalsin, S. J.; Hillmyer, M. A.; Bates, F. S. – Molecular Weight Dependence of Zero-Shear Viscosity in Atactic Polypropylene Bottlebrush Polymers – ACS Macro Lett. 2014, 3, 423–427. DOI: 10.1021/mz500082h

(280) Martinez, H.; Ren, N. Matta, M. E.; Hillmyer, M. A. – Ring-opening metathesis polymerization of 8-membered cyclic olefins – Polym. Chem. 2014, 5, 3507–3532. DOI: 10.1039/C3PY01787G

(279) Delgado, P. A.; Hillmyer, M. A. – Combining block copolymers and hydrogen bonding for poly(lactide) toughening – RSC Adv. 2014, 4, 13266–13273. DOI: 10.1039/C4RA00150H

(278) Xu, Y.; Thurber, C. M.; Macosko, C. W.; Lodge, T. P.; Hillmyer, M. A. – Poly(methyl methacrylate)-block-polyethylene-block-poly(methyl methacrylate) Triblock Copolymers as Compatibilizers for Polyethylene/Poly(methyl methacrylate) Blends – Ind. Eng. Chem. Res. 2014, 53, 4718–4725.
DOI: 10.1021/ie4043196

(277) Tang, D.; Macosko, C. W.; Hillmyer, M. A. – Thermoplastic polyurethane elastomers from bio-based poly(δ-decalactone) diols – Polym. Chem. 2014, 5, 3231–3237. DOI: 10.1039/C3PY01120H

(276) Kennemur, J. G.; Yao, L.; Bates, F. S.; Hillmyer, M. A. – Sub-5 nm Domains in Ordered Poly(cyclohexylethylene)-block-poly(methyl methacrylate) Block Polymers for Lithography – Macromolecules 2014, 47, 1411–1418. DOI: 10.1021/ma4020164

(275) Gallagher, J. J.; Hillmyer, M. A.; Reineke, T. R. – Degradable Thermosets from Sugar-Derived Dilactones – Macromolecules 2014, 47, 498–505. DOI: 10.1021/ma401904x

(274) Martinez, H.; Hillmyer, M. A. – Carboxy-Telechelic Polyolefins in Cross-Linked Elastomers – Macromolecules 2014, 47, 479–485. DOI: 10.1021/ma402397b

(273) Schulze, M. W.; McIntosh, L. D.; Hillmyer, M. A.; Lodge, T. P. – High-Modulus, High-Conductivity Nanostructured Polymer Electrolyte Membranes via Polymerization-Induced Phase Separation – Nano Lett. 2014, 14, 122–126. DOI: 10.1021/nl4034818

(272) Yin, L.; Hillmyer, M. A. – Preparation and Performance of Hydroxypropyl Methylcellulose Esters of Substituted Succinates for in Vitro Supersaturation of a Crystalline Hydrophobic Drug – Mol. Pharmaceutics 2014, 11, 175−185. DOI: 10.1021/mp4003656

(271) Seo, M.; Hillmyer, M. A. – RAFT copolymerization of acid chloride-containing
monomers – Polymer Chem. 2014, 5, 213–219. DOI: 10.1039/C3PY00867C

(270) Kim, J. C.; Seo, M.; Hillmyer, M. A.; Francis. L. F. – Magnetic Microrheology of Block Copolymer Solutions – ACS Appl. Mater. Interfaces 2013, 5, 11877–11883. DOI: 10.1021/am403569f

(269) Healy, A. T.; Boudouris, B. W.; Frisbie, C. D.; Hillmyer, M. A.; Blank, D. A. – Intramolecular Exciton Diffusion in Poly(3-hexylthiophene) – J. Phys. Chem. Lett. 2013, 4, 3445−3449. DOI: 10.1021/jz401694j

(268) Knight, S. C.; Schaller, C. P.; Tolman, W. B.; Hillmyer, M. A. – Renewable carvone-based polyols for use in polyurethane thermosets – RSC Advances 2013, 3, 20399–20404. DOI: 10.1039/C3RA44084B

(267) Jeong, H.; Kozera, D. J.; Schrock, R. R.; Smith, S. J.; Zhang, J.; Ren, N.; Hillmyer, M. A. – Z-Selective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes by Monoaryloxide Pyrrolide Imido Alkylidene (MAP) Catalysts of Molybdenum and Tungsten – Organometallics 2013, 32, 4843−4850.


DOI: 10.1021/om400583t

(266) Bertrand, A.; Hillmyer, M. A. – Nanoporous polylactide by olefin metathesis degradation – J. Am. Chem. Soc. 2013, 135, 10918–10921. DOI: 10.1021/ja4050532

(265) Sinturel, C.; Vayer, M.; Morris, M.; Hillmyer, M. A. – Solvent Vapor Annealing of Block Polymer Thin Films – Macromolecules 2013, 46, 5399−5415. DOI: 10.1021/ma400735a

(264) Seo, M.; Murphy, C. J.; Hillmyer, M. A. – One-Step Synthesis of Cross-Linked Block Polymer Precursor to a Nanoporous Thermoset – ACS Macro Lett. 2013, 2, 617−620. DOI: 10.1021/mz400192f

(263) Speros, J. C.; Martinez, H.; Paulsen, B. D.; White, S. P.; Bonifas, A. D.; Goff, P. C.; Frisbie, C. D.; Hillmyer, M. A. – Effects of Olefin Content and Alkyl Chain Placement on Optoelectronic and Morphological Properties in Poly(thienylene vinylenes) – Macromolecules 2013, 46, 5184−5194. DOI: 10.1021/ma4009115

(262) Engbrecht, J.; Green, D.; Hillmyer, M. A.; Olson, D.; Todd, E. M. – Positron Lifetime Spectroscopy in Ordered Nanoporous Polymers – J. Polym. Sci. Polym. Phys. 2013, 51, 1157–1161. DOI: 10.1002/polb.23314

(261) Kennemur, J. G.; Hillmyer, M. A.; Bates, F. S. – Rheological Evidence of Composition Fluctuations in an Unentangled Diblock Copolymer Melt near the Order-Disorder Transition – ACS Macro Lett. 2013, 2, 496–500.
DOI: 10.1021/mz4001892

(260) Querelle, S. E.; Jackson, E. A.; Cussler, E. L.; Hillmyer, M. A. – Ultrafiltration membranes with a thin poly(styrene)-b-poly(isoprene) selective layer – ACS Appl. Mater. Interfaces 2013, 5, 5044–5050.


DOI: 10.1021/am400847m

(259) Petersen, M. A.; Hillmyer, M. A.; Kokkoli, E. – Bioresorbable Polymersomes for Targeted Delivery of Cisplatin – Bioconjugate Chem. 2013, 24, 533–543. DOI: 10.1021/bc3003259

(258) Pitet, L. M.; Zhang, J.; Hillmyer, M. A. – Sequential ROMP of cyclooctenes as a route to linear polyethylene block copolymers – Dalton Trans. 2013, 42, 9079–9088. DOI: 10.1039/C2DT32695G

(257) Zhang, J.; Matta, M. E.; Martinez, H.; Hillmyer, M. A. – Precision Vinyl Acetate/Ethylene (VAE) Copolymers by ROMP of Acetoxy-Substituted Cyclic Alkenes – Macromolecules 2013, 46, 2535–2543.


DOI: 10.1021/ma400092z

(256) Jackson, E. A.; Lee, Y.; Hillmyer, M. A. – ABAC Tetrablock Terpolymers for Tough Nanoporous Filtration Membranes – Macromolecules 2013, 46, 1484–1491. DOI: 10.1021/ma302414w

(255) Kato, T.; Hillmyer, M. A. – Functionalized Nanoporous Polyethylene Derived from Miscible Block Polymer Blends – ACS Appl. Mater. Interfaces 2013, 5, 291–300. DOI: 10.1021/am3020907

(254) Kobayashi, S.; Kim, H.; Macosko, C. W.; Hillmyer, M. A. – Functionalized linear low-density polyethylene by
ring-opening metathesis polymerization – Polymer Chem. 2013, 4, 1193–1198. DOI: 10.1039/C2PY20883K

(253) Moughton, A. O.; Sagawa, T.; Gramlich, W. M.; Seo, M.; Lodge, T. P.; Hillmyer, M. A. – Synthesis of block polymer miktobrushes – Polymer Chem. 2013, 4, 166–173. DOI: 10.1039/C2PY20656K

(252) Koonar, I.; Zhou, C.; Hillmyer, M. A.; Lodge, T. P.; Siegel, R. A. – ABC Triblock Terpolymers Exhibiting Both Temperature- and pH-Sensitive Micellar Aggregation and Gelation in Aqueous Solution –Langmuir 2012, 28, 17785−17794. DOI: 10.1021/la303712b

(251) Xu, Y.; Thurber, C. M.; Lodge, T. P.; Hillmyer, M. A. – Synthesis and Remarkable Efficacy of Model Polyethylene-graft-poly(methyl methacrylate) Copolymers as Compatibilizers in Polyethylene/Poly(methyl methacrylate) Blends – Macromolecules 2012, 45, 9604−9610. DOI: 10.1021/ma302187b [Correction: DOI: 10.1021/acs.macromol.5b02640]

(250) Yin, L.; Lodge, T. P.; Hillmyer, M. A. – A stepwise “micellization–crystallization” route to oblate ellipsoidal, cylindrical, and bilayer micelles with polyethylene cores in water – Macromolecules 2012, 45, 9460−9467.


DOI: 10.1021/ma302069s

(249) Shin, J.; Lee, Y.; Tolman, W. B.; Hillmyer, M. A. – Thermoplastic Elastomers Derived from Menthide and Tulipalin A – Biomacromolecules 2012, 13, 3833−3840. DOI: 10.1021/bm3012852

(248) Chaffin, K. A.; Buckalew, A. J.; Schley, J. L.; Chen, X.; Jolly, M.; Alkatout, J. A.; Miller, J. P.; Untereker, D. F.; Hillmyer, M. A.; Bates, F. S. – The Influence of Water on the Structure and Properties of PDMS-containing Multiblock Polyurethanes – Macromolecules 2012, 45, 9110−9120. DOI: 10.1021/ma301965y

(247) Martinez, H.; Miró, P.; Charbonneau, P.; Hillmyer, M. A.; Cramer, C. J. – Selectivity in Ring-opening Metathesis Polymerization of Z-Cyclooctenes Catalyzed by a Second-generation Grubbs Catalyst – ACS Catalysis 2012, 2, 2547–2556. DOI: 10.1021/cs300549u

(246) Zhang, J.; Matta, M. E.; Hillmyer, M. A. – Synthesis of Sequence-Specific Vinyl Copolymers by Regioselective ROMP of Multiply Substituted Cyclooctenes – ACS Macro Lett. 2012, 1, 1383–1387. DOI: 10.1021/mz300535r

(245) Gurusamy-Thangavelu, S. A.; Emond, S.; Kulshrestha, A.; Hillmyer, M. A.; Macosko, C. W.; Tolman, W. B.; Hoye, T. R. – Polyurethanes based on renewable polyols from bioderived lactones – Polymer Chem. 2012, 3, 2941–2948. DOI: 10.1039/C2PY20454A

(244) Ha, J. -M.; Hamilton, B. D.; Hillmyer, M. A.; Ward, M. D. – Alignment of Organic Crystals under Nanoscale Confinement – Cryst. Growth Des. 2012, 12, 4494–4504. DOI: 10.1021/cg3006635

(243) Kennemur, J. G.; Hillmyer, M. A.; Bates, F. S. – Synthesis, Thermodynamics, and Dynamics of Poly(4-tert-butylstyrene-b-methyl methacrylate) – Macromolecules 2012, 45, 7228−7236. DOI: 10.1021/ma301047y

(242) Speros, J. C.; Paulsen, B. D.; Slowinski, B. S.; Frisbie, C. D.; Hillmyer, M. A. – Band Gap and HOMO Level Control in Poly(thienylene vinylene)s Prepared by ADMET Polymerization – ACS Macro Lett. 2012, 1, 986−990.
DOI: 10.1021/mz300326k

(241) Rodwogin, M. D.; Baruth, A.; Jackson, E. A.; Leighton, C.; Hillmyer, M. A. – Nanoscale Rings from Silicon-Containing Triblock Terpolymers – ACS Appl. Mater. Interfaces 2012, 4, 3550–3557.


DOI: 10.1021/am300603x

(240) Zhou, C.; Hillmyer, M. A.; Lodge, T. P. – Efficient Formation of Multicompartment Hydrogels by Stepwise Self-Assembly of Thermoresponsive ABC Triblock Terpolymers – J. Am. Chem. Soc. 2012, 134, 10365–10368.


DOI: 10.1021/ja303841f

(239) Ding, K.; Miranda, M. O; Moscato-Goodpaster, B.; Ajellal, N.; Breyfogle, L. E.; Hermes, E. D.; Schaller, C. P.; Roe, S. E.; Cramer, C. J.; Hillmyer, M. A.; Tolman, W. B. – The Roles of Monomer Binding and Alkoxide Nucleophilicity in Aluminum-Catalyzed Polymerization of -Caprolactone – Macromolecules 2012, 45, 5387–5396. DOI: 10.1021/ma301130b

(238) Touris, A.; Lee, S.; Hillmyer, M. A.; Bates, F. S. – Synthesis of Tri- and Multiblock Polymers with Asymmetric Poly(ethylene oxide) End-Blocks – ACS Macro Lett. 2012, 1, 768–771. DOI: 10.1021/mz3002319

(237) Seo, M.; Hillmyer, M. A. – Reticulated Nanoporous Polymers by Controlled Polymerization-Induced Microphase Separation – Science 2012, 336, 1422–1425. DOI: 10.1126/science.1221383

(236) Yin, L.; Dalsin, M. C.; Sizovs, A.; Reineke, T. M.; Hillmyer, M. A. – Glucose-functionalized, serum-stable polymeric micelles from the combination of anionic and RAFT polymerizations – Macromolecules 2012, 45, 4322–4332. DOI: 10.1021/ma300218n

(235) Amendt, M. A.; Pitet, L. M.; Moench, S.; Hillmyer, M. A. – Reactive triblock polymers from tandem ring-opening polymerizations for nanostructured vinyl thermosets – Polymer Chem. 2012, 3, 1827–1837.


DOI: 10.1039/C1PY00450F

(234) Hamilton, B. D.; Ha, J.–M.; Hillmyer, M. A.; Ward, M. D. – Manipulating Crystal Growth and Polymorphism by Confinement in Nanoscale Crystallization Chambers – Acc. Chem. Res. 2012, 45, 414–423. DOI: 10.1021/ar200147v

(233) Gramlich, W. M.; Theryo, G.; Hillmyer, M. A. – Copolymerization of Isoprene and Hydroxyl Containing Monomers by Controlled Radical and Emulsion Methods – Polym. Chem. 2012, 3, 1510–1516.
DOI: 10.1039/C2PY20072D

(232) Du, A.; Koo, D.; Theryo, G.; Hillmyer, M. A.; Cairncross, R. A. – Water Transport and Clustering Behavior in Homopolymer and Graft Copolymer Polylactide – J. Membrane Sci. 2012, 396, 50–56.


DOI: 10.1016/j.memsci.2011.12.030

(231) Bates, F. S.; Hillmyer, M. A.; Lodge, T. P.; Bates, C. M.; Delaney, K. T.; Fredrickson, G. H. – Multiblock Polymers: Panacea or Pandora's Box? – Science 2012, 336, 434–440. DOI: 10.1126/science.1215368

(230) Speros, J. C.; Paulsen, B. D.; White, S. P.; Wu, Y.; Jackson, E. A.; Slowinski, B. S.; Frisbie, C. D.; Hillmyer, M. A. – An ADMET route to low band gap poly(3-hexadecylthienylene vinylene): A systematic study of molecular weight on photovoltaic performance – Macromolecules 2012, 45, 2190−2199. DOI: 10.1021/ma3000434

(229) Miranda, M. O.; Pietrangelo, A.; Hillmyer, M. A.; Tolman, W. B. – Catalytic decarbonylation of biomass-derived carboxylic acids as an efficient route to commodity monomers – Green Chemistry 2012, 14, 490-494.


DOI: 10.1039/C2GC16115J

(228) Martello, M. T.; Burns, A.; Hillmyer, M. A. – Bulk ring-opening transesterification polymerization of the renewable δ-decalactone using an organocatalyst – ACS Macro Lett. 2012, 1, 131–135. DOI: 10.1021/mz200006s

(227) Moughton, A. O.; Hillmyer, M. A.; Lodge, T. P. – Multicompartment block polymer micelles – Macromolecules 2012, 45, 2–19. DOI: 10.1021/ma201865s

(226) Wang, Y.; Pitet, L. M.; Finlay, J. A.; Brewer, L.; Cone, G.; Betts, D. E.; Callow, M. E.; Callow, J. A.; Wendt, D.; Hillmyer, M. A.; DeSimone, J. M. – Role of Hydrophilic Chain Length In Amphiphilic Perfluoropolyether/ Poly(ethylene glycol) Networks: Towards High-Performance Nonfouling Coatings – Biofouling 2011, 27, 1139–1150.


DOI: 10.1080/08927014.2011.629344

(225) Seo, M.; Amendt, M. A.; Hillmyer, M. A. – Crosslinked nanoporous materials from reactive and multifunctional block polymers – Macromolecules 2011, 44, 9310–9318. DOI: 10.1021/ma2013942

(224) Martello, M. T.; Hillmyer, M. A. – Polylactide-Poly(6-methyl-ε-caprolactone)-Polylactide Thermoplastic Elastomers – Macromolecules 2011, 44, 8537–8545. DOI: 10.1021/ma201063t

(223) Stevens, D. M.; Speros, J. C.; Hillmyer, M. A.; Frisbie, C. D. – Relationship Between Diode Saturation Current and Open Circuit Voltage in Poly(3-alkylthiophene) Solar Cells as a Function of Device Architecture, Processing Conditions, and Alkyl Side Chain Length – J. Phys. Chem. C. 2011, 115, 20806–20816. DOI: 10.1021/jp2070612

(222) Vayer, M.; Nguyen, T. H.; Grosso, D.; Boissiere, C.; Hillmyer, M. A.; Sinturel, C. – Characterization of nanoporous polystyrene thin films by environmental ellipsometric porosimetry – Macromolecules 2011, 44, 8892–8897. DOI: 10.1021/ma201497z

(221) Davis, E. M.; Theryo, G.; Hillmyer, M. A.; Cairncross, R. A.; Elabd, Y. A. – Liquid Water Transport in Polylactide Homo and Graft Copolymers – ACS Appl. Mater. Interfaces 2011, 3, 3997–4006. DOI: 10.1021/am2008618

(220) Baruth, A.; Rodwogin, M.D.; Shankar, A.; Erickson, M. J.; Hillmyer, M. A.; Leighton, C. – Non-liftoff block copolymer lithography of 25 nm magnetic nanodot arrays – ACS Appl. Mater. Interfaces 2011, 3, 3472–3481.
DOI: 10.1021/am200693x

(219) Robertson, M. L.; Paxton, J.; Hillmyer, M. A. – Tough Blends of Polylactide and Castor Oil – ACS Appl. Mater. Interfaces 2011, 3, 3402–3410. DOI: 10.1021/am2006367

(218) Gramlich, W. M.; Hillmyer, M. A. – Catalytic synthesis and post polymerization functionalization of conjugated polyisoprene – Polym. Chem. 2011, 2, 2062–2067. DOI: 10.1039/C1PY00147G

(217) Amendt, M. A.; Roerdink, M.; Moench, S.; Phillip, W. A.; Cussler, E. L.; Hillmyer, M. A. – Functionalized nanoporous membranes from reactive triblock terpolymers – Aust. J. Chem. 2011, 64, 1074–1082.


DOI: 10.1071/CH11130

(216) Crossland, E. J. W.; Cunha, P.; Steiner, U.; Hillmyer, M. A.; Ludwigs, S. – In-situ electrochemical monitoring of selective etching in ordered mesoporous block-copolymer templates – ACS Appl. Mater. Interfaces 2011, 3, 1375–1379. DOI: 10.1021/am2000505

(215) Yin, L.; Hillmyer, M. A. – Disk-like micelles in water from polyethylene-containing diblock copolymers – Macromolecules 2011, 44, 3021–3028. DOI: 10.1021/ma200242b

(214) Pitet, L. M.; Hillmyer, M. A. – Carboxy-telechelic polyolefins by ROMP with maleic acid – Macromolecules 2011, 44, 2378–2381. DOI: 10.1021/ma102975r

(213) Kim, H.; Kobayashi, S.; AbdurRahim, M. A.; Zhang, M. J.; Khusainova, A.; Hillmyer, M. A.; Abdala, A. A.; Macosko, C. W. – Graphene/polyethylene nanocomposites – Polymer 2011, 52, 1837–1846. DOI: 10.1016/j.polymer.2011.02.017

(212) Kobayashi, S.; Pitet, L. M.; Hillmyer, M. A. – Regio- and Stereoselective Ring-Opening Metathesis Polymerization of 3-Substituted Cyclooctenes – J. Am. Chem. Soc. 2011, 133, 5794–5797. DOI: 10.1021/ja201644v

(211) Zhou, C.; Hillmyer, M. A.; Lodge, T. P. – Micellization and micellar aggregation of poly(ethylene-alt-propylene)-b-poly(ethylene oxide)-b-poly(N-isopropylacrylamide) triblock terpolymers in water – Macromolecules 2011, 44, 1635–1641. DOI: 10.1021/ma102786q

(210) Kobayashi, S.; Song, J.; Silvis, C.; Macosko, C. W.; Hillmyer, M. A. – Amino-functionalized Polyethylene for Enhancing the Adhesion Between Polyolefins and Polyurethanes – Ind. Eng. Chem. Res. 2011, 50, 3274–3279.


DOI: 10.1021/ie102005q

(209) Shin, J.; Martello, M. T.; Shrestha, M.; Wissinger, J. E.; Tolman, W. B.; Hillmyer, M. A. – Pressure-Sensitive Adhesives from Renewable Triblock Copolymers – Macromolecules 2011, 44, 87–94. DOI: 10.1021/ma102216d

(208) Lowe, J. R.; Martello, M. T.; Tolman, W. B.; Hillmyer, M. A. – Functional Biorenewable Polyesters from Carvone-derived Lactones – Polym. Chem. 2011, 2, 702–708. DOI: 10.1039/C0PY00283F

(207) Hu, Z.; Pitet, L. M.; Hillmyer, M. A.; DeSimone, J. M. – High Modulus, Low Surface Energy, Photochemically Cured Materials from Liquid Precursors – Macromolecules 2010, 43, 10397–10405. DOI: 10.1021/ma101180k

(206) Querelle, S. E.; Chen, L.; Hillmyer, M. A.; Cussler, E. L.; Nijmeijer, K.; Wessling, M. – Block Copolymer Derived Membranes for Enhanced Carbon Dioxide–Methane Separations – Ind. Eng. Chem. Res. 2010, 49, 12051–12059.
DOI: 10.1021/ie100461k

(205) Petersen, M. A.; Yin, L.; Kokkoli, E.; Hillmyer, M. A. – Synthesis and Characterization of Reactive PEO-PMCL Polymersomes – Polym. Chem. 2010, 1, 1281–1290. DOI: 10.1039/C0PY00143K

(204) Faustini, M.; Vayer, M.; Marmiroli, B.; Hillmyer, M. A.; Amenitsch, H.; Sinturel, C.; Grosso, D. – Bottom-up approach towards titanosilicate mesoporous Pillared Planar Nanochannels (PPNs) for nanofluidic applications – Chem. Mater. 2010, 22, 5687–5694. DOI: 10.1021/cm101502n

(203) Pitet, L. M.; Chamberlain, B. M.; Hauser, A. W.; Hillmyer, M. A. – Synthesis of Linear, H-Shaped, and Arachnearm Block Copolymers by Tandem Ring-Opening Polymerizations – Macromolecules 2010, 43, 8018–8025.


DOI: 10.1021/ma1014325

(202) Theryo, G.; Jing, F.; Pitet, L. M.; Hillmyer, M. A. – Tough polylactide graft copolymers – Macromolecules 2010, 43, 7394–7397. DOI: 10.1021/ma101155p

(201) Phillip, W. A.; Hillmyer, M. A.; Cussler, E. L. – Cylinder Orientation Mechanism in Block Copolymer Thin Films Upon Solvent Evaporation – Macromolecules 2010, 43, 7763–7770. DOI: 10.1021/ma1012946

(200) Liu, J.; Thompson, Z. J.; Sue, H. -J.; Bates, F. S.; Hillmyer, M. A.; Dettloff, M.; Jacob, G.; Verghese, N.; Pham, H. – Toughening of Epoxies with Block Copolymer Micelles of Worm-Like Morphology – Macromolecules 2010, 43, 7238–7243. DOI: 10.1021/ma902471g

(199) Pietrangelo, A.; Knight, S. C.; Gupta, A. K.; Yao, L. J.; Hillmyer, M. A.; Tolman, W. B. – Mechanistic Study of the Stereoselective Polymerization of D,L-Lactide using Indium(III) Halides – J. Am. Chem. Soc. 2010, 132, 11649–11657. DOI: 10.1021/ja103841h

(198) Fiore, G. L.; Jing, F.; Young Jr., V. G.; Cramer, C. J.; Hillmyer, M. A. – High Tg Aliphatic Polyesters by the Polymerization of Spirolactide Derivatives – Polym. Chem., 2010, 6, 870–877. DOI: 10.1039/C0PY00029A

(197) Kobayashi, S.; Macosko, C. W.; Hillmyer, M. A. – Model linear low density polyethylenes from the ROMP of 5-hexyl-1-cyclooctene – Aust. J. Chem. 2010, 63, 1201–1209. DOI: 10.1071/CH10039

(196) Pitet, L. M.; Amendt, M. A.; Hillmyer, M. A. – Nanoporous Linear Polyethylene from a Block Polymer Precursor – J. Am. Chem. Soc. 2010, 132, 8230–8231. DOI: 10.1021/ja100985d

(195) Taribagil, R.; Hillmyer, M. A.; Lodge, T. P. – Hydrogels from ABA and ABC Triblock Polymers – Macromolecules 2010, 43, 5396–5404. DOI: 10.1021/ma100464z

(194) Saito, N.; Liu, C.; Lodge, T. P.; Hillmyer, M. A. – Multicompartment Micelle Morphology Evolution in Degradable Miktoarm Star Terpolymers – ACS Nano 2010, 4, 1907–1912. DOI: 10.1021/nn9016873

(193) Amendt, M. A.; Chen, L.; Hilmyer, M. A. – The formation of nanostructured poly(dicyclopentadiene) thermosets using reactive block polymers – Macromolecules 2010, 43, 3924–3934. DOI: 10.1021/ma100318j

(192) Vayer, M.; Hillmyer, M. A.; Dirany, M.; Thevenin, G.; Erre, R.; Sinturel, C. – Perpendicular orientation of cylindrical domains upon solvent annealing thin films of poly(styrene)-b-poly(lactide) – Thin Solid Films 2010, 518, 3710–3715. DOI: 10.1016/j.tsf.2009.10.015

(191) Boudouris, B. W.; Frisbie, C. D.; Hillmyer, M. A. – Polylactide-Polythiophene-Polylactide Triblock Copolymers – Macromolecules 2010, 43, 3566–3569. DOI: 10.1021/ma1002134

(190) Phillip, W. A.; O’Neill B.; Rodwogin, M.; Hillmyer, M. A.; Cussler, E. L. – Self-Assembled Block Copolymer Thin Films as Water Filtration Membranes – ACS Appl. Mater. Interfaces 2010, 2, 847–853. DOI: 10.1021/am900882t

(189) Gramlich, W. M.; Robertson, M. L.; Hillmyer, M. A. – Reactive Compatibilization of Poly(L-lactide) and Conjugated Soybean Oil – Macromolecules 2010, 43, 2313–2321. DOI: 10.1021/ma902449x

(188) Crossland, E. J. W.; Cunha, P.; Scroggins, S.; Moratti, S.; Yurchenko, O.; Steiner, U.; Hillmyer, M. A.; Ludwigs, S. – Soft-etch mesoporous hole-conducting block copolymer templates – ACS Nano 2010, 4, 962–966.


DOI: 10.1021/nn901447a

(187) Robertson, M. L.; Chang, K.; Gramlich, W. M.; Hillmyer, M .A. – Toughening of Polylactide with Polymerized Soybean Oil – Macromolecules 2010, 43, 1807–1814. DOI: 10.1021/ma9022795

(186) Rodwogin, M. D.; Spanjers, C. S.; Leighton, C.; Hillmyer, M. A. – Polylactide-polydimethylsiloxane block polymers as multifunctional materials for nanolithographic applications – ACS Nano 2010, 4, 725–732.
DOI: 10.1021/nn901190a

(185) Crossland, E. J. W.; Ludwigs, S.; Hillmyer, M. A.; Steiner, U. – Control of gyroid forming block copolymer templates: effects of an electric field and surface topography – Soft Matter 2010, 6, 670–676.


DOI: 10.1039/b914421h

(184) Kim, J. -Y.; Qin, Y.; Stevens, D. M.; Kalihari, V.; Hillmyer, M. A.; Frisbie, C. D. – High Open-Circuit Voltage Photovoltaic Cells with a Low Bandgap Copolymer of Isothianaphthene, Thiophene and Benzothiadiazole Units – J. Phys. Chem. C 2009, 113, 21928–21936. DOI: 10.1021/jp9079926

(183) Liu, C.; Hillmyer, M. A.; Lodge, T. P. – Multicompartment Micelles from pH Responsive Miktoarm Star Block Terpolymers – Langmuir 2009, 25, 13718–13725. DOI: 10.1021/la900845u

(182) Ha, J. -M.; Hamilton, B. D.; Hillmyer, M. A.; Ward, M. D. – Phase Behavior and Polymorphism of Organic Crystals Confined within Nanoscale Chambers – Crystal Growth and Design 2009, 9, 4766–4777.


DOI: 10.1021/cg9006185

(181) Chang, K.; Robertson, M. L.; Hillmyer, M. A. – Morphology of Polylactide / Soybean Oil Blends Compatibilized by Block Copolymers – ACS Appl. Mater. Interfaces 2009, 1, 2390–2399. DOI: 10.1021/am900514v

(180) Wanamaker, C. L.; Bluemle; M. J.; Pitet, L. M.; O’Leary, L. E.; Tolman, W. B.; Hillmyer, M. A. – Consequences of Polylactide Stereochemistry on the Properties of Polylactide-Polymenthide-Polylactide Thermoplastic Elastomers – Biomacromolecules 2009, 10, 2904–2911. DOI: 10.1021/bm900721p

(179) Meuler, A. J.; Hillmyer, M. A.; Bates, F. S. – Ordered Network Mesostructures in Block Polymer Materials – Macromolecules 2009, 42, 7221–7250. DOI: 10.1021/ma9009593

(178) Hu, Z.; Finlay, J. A.; Chen, L.; Betts, D. E.; Hillmyer, M. A.; Callow, M. E.; Callow, J. A.; DeSimone, J. M. – Photochemically Crosslinked Perfluoropolyether-based Elastomers: Synthesis, Physical Characterization and Biofouling Evaluation – Macromolecules 2009, 42, 6999–7007. DOI: 10.1021/ma901227k

(177) Wanamaker, C. L.; Tolman, W. B.; Hillmyer, M. A. – Poly(d-lactide)-Poly(menthide)-Poly(d-lactide) Triblock Copolymers as Crystal Nucleating Agents for Poly(l-lactide) – Macromol. Symp. 2009, 283–284, 130–138.


DOI: 10.1002/masy.200950917 (Also published in "New Trends in Polymer Science" Krzysztof Matyjaszewski, Rigoberto Advincula, Enrique Saldívar-Guerra, Gabriel Luna-Bárcenas (Editors), Wiley-VCH, Weinheim, 2009. ISBN: 3-527-32735-5.)

(176) Qin, Y.; Hillmyer, M. A. – Poly(3-hexyl-2,5-thienylene vinylene) by ADMET Polymerization of a Dipropenyl Monomer – Macromolecules 2009, 42, 6429–6432. DOI: 10.1021/ma9009824

(175) Chen, L.; Hallinan, T.; Elabd, Y. A.; Hillmyer, M. A. – Highly Selective Polymer Electrolyte Membranes From Reactive Block Polymers – Macromolecules 2009, 42, 6075–6085. DOI: 10.1021/ma901272s

(174) Crossland, E. J. W.; Kamperman, M.; Nedelcu, M.; Ducati, C.; Wiesner, U.; Smilgies, D. -M.; Toombes, G. E. S.; Hillmyer, M. A.; Ludwigs, S.; Steiner, U.; Snaith, H. J. – A bicontinuous double gyroid hybrid solar cell – Nano Letters 2009, 9, 2807–2812. DOI: 10.1021/nl803174p

(173) Crossland, E. J. W.; Nedelcu, M.; Ducati, C.; Ludwigs, S.; Hillmyer, M. A.; Steiner, U.; Snaith, H. J. – Block copolymer morphologies in dye-sensitized solar cells: probing the photovoltaic structure-function relation – Nano Letters 2009, 9, 2813–2819. DOI: 10.1021/nl800942c

(172) Meuler, A. J.; Ellison, C. J.; Qian, J.; Evans, C. M.; Hillmyer, M. A.; Bates, F. S. – Polydispersity Effects in Poly(isoprene–b–styrene–b–ethylene oxide) Triblock Terpolymers – J. Chem. Phys. 2009, 130, 234903.


DOI: 10.1063/1.3140205

(171) Lowe, J. R.; Tolman, W. B.; Hillmyer, M. A. – Oxidized Dihydrocarvone as a Renewable Multifunctional Monomer for the Synthesis of Shape Memory Polyesters – Biomacromolecules 2009, 10, 2003–2008.


DOI: 10.1021/bm900471a

(170) Stevens, D. M.; Qin, Y.; Hillmyer, M. A.; Frisbie, C. D. – Enhancement of the Morphology and Open Circuit Voltage in Bilayer Polymer/Fullerene Solar Cells – J. Phys. Chem. C 2009, 113, 11408–11415.


DOI: 10.1021/jp902198y

(169) Boudouris, B. W.; Molins, F.; Blank, D. A.; Frisbie, C. D.; Hillmyer, M. A. – Synthesis, Optical Properties, and Microstructure of a Fullerene-terminated Poly(3-hexylthiophene) – Macromolecules 2009, 42, 4118–4126.


DOI: 10.1021/ma900312a

(168) Chen, L.; Hillmyer, M. A. – Mechanically and Thermally Robust Ordered Nanoporous Monoliths Using Norbornene-Functional Block Polymers – Macromolecules 2009, 42, 4237–4243. DOI: 10.1021/ma900389n

(167) Kim, J. Y.; Qin, Y.; Stevens, D. M.; Ugurlu, O.; Kalihari, V.; Hillmyer, M. A.; Frisbie, C. D. – Low Bandgap Poly(thienylenevinylene)/Fullerene Bulk-Heterojunction Photovoltaic Cells – J. Phys. Chem. C 2009, 113, 10790–10797. DOI: 10.1021/jp902199q

(166) Kobayashi, S. Lu, C.; Hoye, T. R.; Hillmyer, M. A. – Controlled Polymerization of a Cyclic Diene Prepared from the Ring-Closing Metathesis of a Naturally Occurring Monoterpene – J. Am. Chem. Soc. 2009, 131, 7960–7961.


DOI: 10.1021/ja9027567

(165) Zupancich, J. A.; Bates, F. S.; Hillmyer, M. A. – Synthesis and Self-Assembly of RGD-functionalized PEO-PB Amphiphiles – Biomacromolecules 2009, 10, 1554–1563. DOI: 10.1021/bm900149b

(164) Phillip, W. A.; Martono, E.; Chen, L.; Hillmyer, M. A.; Cussler, E. L. – Seeking an Ammonia Selective Membrane Based on Nanostructured Sulfonated Block Copolymers – J. Membr. Sci. 2009, 337, 39–46.
DOI: 10.1016/j.memsci.2009.03.013

(163) Pitet, L. M.; Hillmyer, M. A. – Combining ROMP and ROP to form ABA triblock copolymers from 1,5-cyclooctadiene and D,L-lactide – Macromolecules 2009, 42, 3674–3680. DOI: 10.1021/ma900368a

(162) Pietrangelo, A.; Hillmyer, M. A.; Tolman, W. B. – Stereoselective and Controlled Polymerization of rac-Lactide Using Indium(III) Trichloride – Chem. Comm. 2009, 2736–2737. DOI: 10.1039/b902968k

(161) Nuxoll, E. E.; Hillmyer, M. A.; Wang, R.; Leighton, C.; Siegel, R. A. – Composite Block Polymer−Microfabricated Silicon Nanoporous Membrane – ACS Applied Materials & Interfaces 2009, 1, 888–893.


DOI: 10.1021/am900013v

(160) Thompson, Z. J.; Hillmyer, M. A.; Liu, J.; Sue, H. -J.; Dettloff, M.; Bates, F. S. – Block Copolymer Toughened Epoxy: Role of Crosslink Density – Macromolecules 2009, 42, 2333–2335. DOI: 10.1021/ma900061b

(159) Taribagil, R.; Hillmyer, M. A.; Lodge, T. P. – A Compartmentalized Hydrogel from a Linear ABC Terpolymer – Macromolecules 2009, 42, 1796–1800. DOI: 10.1021/ma8025089

(158) Hamilton, B. D.; Weissbuch, I.; Lahav, M.; Hillmyer, M. A.; Ward, M. D. – Manipulating Crystal Orientation in Nanoscale Cylindrical Pores by Stereochemical Inhibition – J. Am. Chem. Soc. 2009, 131, 2588–2596.


DOI: 10.1021/ja807193s

(157) Phillip, W. A.; Amendt, M.; O,Neill, B.; Chen, L.; Hillmyer, M. A.; Cussler, E.L. – Diffusion and flow across nanoporous poly(dicyclopentadiene)-based membranes – ACS Appl. Mater. Interfaces 2009, 1, 472–480.


DOI: 10.1021/am8001428

(156) Wanamaker, C. L.; Tolman, W. B.; Hillmyer, M. A. – Hydrolytic Degradation Behavior of a Renewable Thermoplastic Elastomer – Biomacromolecules 2009, 10, 443–448. DOI: 10.1021/bm801292v

(155) Saito, N.; Liu, C.; Lodge, T. P.; Hillmyer, M. A. – Multicompartment Micelles from Polyester-Containing ABC Miktoarm Star Terpolymers – Macromolecules 2008, 41, 8815–8822. DOI: 10.1021/ma801001s

(154) Hu, Z.; Chen, L.; Betts, D.; Pandya, A.; Hillmyer, M. A.; DeSimone, J. M. – Optically Transparent, Amphiphilic Networks Based on Blends of Perfluoropolyethers and Poly(ethylene glycol) – J. Am. Chem. Soc. 2008, 130, 14244–14252. DOI: 10.1021/ja803991n

(153) Jing, F.; Hillmyer, M. A. – A Bifunctional Monomer Derived from Lactide for Toughening Polylactide – J. Am. Chem. Soc. 2008, 130, 13826–13827. DOI: 10.1021/ja804357u

(152) Lynd, N. A.; Meuler, A. J.; Hillmyer, M. A. – Polydispersity and Block Copolymer Self-Assembly – Prog. Polym. Sci. 2008, 33, 875–893. DOI: 10.1016/j.progpolymsci.2008.07.003

(151) Liu, C.; Hillmyer, M. A.; Lodge, T. P. – Evolution of Multicompartment Micelles to Mixed Corona Micelles Using Solvent Mixtures – Langmuir 2008, 24, 12001–12009. DOI: 10.1021/la802336k

(150) Mao, H.; Hillmyer, M. A. – Morphological Behavior of Polystyrene-b-Polylactide / Polystyrene-b-Poly(ethylene oxide) Blends – Macromol. Chem. Phys. 2008, 209, 1647–1656. DOI: 10.1002/macp.200800087

(149) Hamilton, B. D.; Hillmyer, M. A.; Ward, M. D. – Glycine Polymorphism in Nanoscale Crystallization Chambers – Crystal Growth and Design 2008, 8, 3368–3375. DOI: 10.1021/cg800326a

(148) Kubo, T.; Wang, R.; Olson, D.; Rodwogin, M.; Hillmyer, M. A.; Leighton, C. – Spontaneous alignment of self-assembled ABC triblock terpolymers for large-area nanolithography – Appl. Phys. Lett. 2008, 93, 133112-1–133112-3. DOI: 10.1063/1.2975370

(147) Meuler, A. J.; Ellison, C. J.; Hillmyer, M. A.; Bates, F. S. – Polydispersity-Induced Stabilization of the Core-Shell Gyroid – Macromolecules 2008, 41, 6272–6275. DOI: 10.1021/ma8010894

(146) Castillo, V.; Müller, A. J.; Lin, M. -C.; Chen, H. -L.; Jeng, U. -S.; Hillmyer, M. A. – Confined crystallization and morphology of melt-segregated PLLA-b-PE and PLDA-b-PE diblock copolymers – Macromolecules 2008, 41, 6154–6164. DOI: 10.1021/ma800859y

(145) Chen, C.; Zhang, H.; Li, S.; Hillmyer, M. A.; Guo, S. – Facile Loading of Metal Ions in the Nanopores of Polymer Thin Films and In Situ Generation of Metal Sulfide Nanoparticle Arrays – Nanotechnology 2008, 19, 365304.
DOI: 10.1088/0957-4484/19/36/365304

(144) Meuler, A. J.; Fleury, G.; Hillmyer, M. A.; Bates, F. S. – Structure and Mechanical Properties of an Orthorhombic Fddd Network-Forming Pentablock Terpolymer – Macromolecules 2008, 41, 5809–5817.


DOI: 10.1021/ma800885s

(143) Qin, Y.; Kim, J. -Y.; Frisbie, C. D.; Hillmyer, M. A. – Distannylated Isothianaphthene: A Versatile Building Block for Low Bandgap Conjugated Polymers – Macromolecules 2008, 41, 5563–5570. DOI: 10.1021/ma8011575

(142) Lynd, N. A.; Hillmyer, M. A.; Matsen, M. W. – Theory of Polydisperse Block Copolymer Melts: Beyond the Schulz-Zimm Distribution – Macromolecules 2008, 41, 4131–4133. DOI: 10.1021/ma800452y

(141) Mahanthappa, M. K.; Hillmyer, M. A.; Bates, F. S. – Mechanical consequences of molecular composition on failure in polyolefin composites containing glassy, elastomeric, and semicrystalline components – Macromolecules 2008, 41, 1341–1351. DOI: 10.1021/ma071196r

(140) Olson, D. A.; Chen, L.; Hillmyer, M. A. – Templating Nanoporous Polymers with Ordered Block Copolymers – Chem. Mater. 2008, 20, 869–890. DOI: 10.1021/cm702239k

(139) Anderson, K. S.; Schreck, K. M.; Hillmyer, M. A. – Toughening Polylactide – Polymer Reviews, 2008, 45, 85–108. DOI: 10.1080/15583720701834216

(138) Boudouris, B. W.; Frisbie, C. D.; Hillmyer, M. A. – Nanoporous poly(3-alkylthiophene) thin films generated from block copolymer templates – Macromolecules 2008, 41, 67–75. DOI: 10.1021/ma071626d

(137) Lynd, N. A.; Hamilton, B. D.; Hillmyer, M. A. – The Role of Polydispersity in the Lamellar Mesophase of Model Diblock Copolymers – J. Poly. Sci. Polym. Phys. 2007, 45, 3386–3393. DOI: 10.1002/polb.21321

(136) Chen, L.; Phillip, W. A.; Cussler, E. L.; Hillmyer, M. A. – Robust Nanoporous Membranes Templated by a Doubly Reactive Block Copolymer – J. Am. Chem. Soc. 2007, 129, 13786–13787. DOI: 10.1021/ja0753041

(135) Wanamaker, C. L.; O’Leary, L. E.; Lynd, N. A.; Hillmyer, M. A.; Tolman, W. B. – Renewable Resource Thermoplastic Elastomers based on Polylactide and Polymenthide – Biomacromolecules 2007, 8, 3634–3640.


DOI: 10.1021/bm700699g

(134) Wells, N. P.; Boudouris, B. W.; Hillmyer, M. A.; Blank, D. A. – Intramolecular Excitation Relaxation and Migration Dynamics in Poly(3-Hexylthiophene) – J. Phys. Chem. B 2007, 111, 15404–15414.


DOI: 10.1021/jp074657j

(133) Schreck, K. M.; Hillmyer, M. A. – Block copolymers and melt blends of polylactide with Nodax™ microbial polyesters: preparation and mechanical properties – J. Biotechnology 2007, 132, 287–295.


DOI: 10.1016/j.jbiotec.2007.03.017

(132) Lynd, N. A.; Hillmyer, M. A. – Effects of Polydispersity on the Order–Disorder Transition in Block Copolymer Melts – Macromolecules 2007, 40, 8050–8055. DOI: 10.1021/ma070962r

(131) Meuler, A. J.; Ellison, C. J.; Qin, J.; Evans, C. M.; Hillmyer, M. A.; Bates, F. S. – Polydispersity-Driven Transition from the Orthorhombic Fddd Network to Lamellae in Poly(isoprene-b-styrene-b-ethylene oxide) Triblock Terpolymers – Macromolecules 2007, 40, 7072–7074. DOI: 10.1063/1.3140205

(130) Silvernail, C. M.; Yao, L. J.; Hill, L. M. R.; Hillmyer, M. A.; Tolman, W. B. – Structural and Mechanistic Studies of Bis(phenolato)amine Zinc(II) Catalysts for the Polymerization of –Caprolactone – Inorg. Chem. 2007, 46, 6565–6574. DOI: 10.1021/ic700581s

(129) Edmonds, W. F.; Hillmyer, M. A.; Lodge, T. P. – Block Copolymer Vesicles in Liquid CO2 – Macromolecules 2007, 40, 4917–4923. DOI: 10.1021/ma0704360

(128) Lodge, T. P.; Taribagil, R.; Yoshida, T.; Hillmyer, M. A – SANS Evidence for the Crosslinking of Wormlike Micelles by a Model Hydrophobically Modified Polymer – Macromolecules 2007, 40, 4728–4731.


DOI: 10.1021/ma070568t

(127) Kubo, T.; Parker, J. S.; Hillmyer, M. A.; Leighton, C. – Characterization of pattern transfer in the fabrication of magnetic nanostructure arrays by block copolymer lithography – Appl. Phys. Lett., 2007, 90, 233113-1–233113-3.


DOI: 10.1063/1.2743900

(126) Yoshida, T.; Taribagil, R.; Hillmyer, M. A.; Lodge, T. P. – Viscoelastic synergy in aqueous mixtures of wormlike micelles and model amphiphilic triblock copolymers – Macromolecules 2007, 40, 1615–1623.


DOI: 10.1021/ma062428+

(125) Mahanthappa, M. K.; Lim, L. S.; Hillmyer, M. A.; Bates, F. S. – Control of Mechanical Behavior in Polyolefin Composites: Integration of Glassy, Rubbery and Semicrystalline Components –Macromolecules 2007, 40, 1585–1593. DOI: 10.1021/ma0617421

(124) Meuler, A. J.; Mahanthappa, M. K.; Hillmyer, M. A.; Bates, F. S. – Synthesis of Monodisperse α–Hydroxy–Polystyrene in Hydrocarbon Media Using a Functional Organolithium – Macromolecules 2007, 40, 760–762.
DOI: 10.1021/ma0623338

(123) Switek, K. A.; Chang, K.; Bates, F. S.; Hillmyer, M. A. – ABA Triblock Copolymers using a Ring–Opening Metathesis Polymerization / Macromolecular Chain Transfer Agent Approach – J. Polym. Sci. Polym. Chem. 2007, 45, 361–373. DOI: 10.1002/pola.21754

(122) Crossland, E. J. W.; Ludwigs, S.; Hillmyer, M. A.; Steiner, U. – Freestanding nanowire arrays from soft–etch block copolymer templates – Soft Matter 2007, 3, 94–98. DOI: 10.1039/B609780D

(121) Müller, A. J.; Castillo, R. V.; Hillmyer, M. A. – Nucleation and Crystallization of PLDA–b–PE and PLLA–b–PE diblock copolymers – Macromol. Symp. 2006, 242, 174 – 181. DOI: 10.1002/masy.200651025

(120) Phillip, W.A.; Rzayev, J.; Hillmyer, M. A.; Cussler, E. L. – Gas and water liquid transport through nanoporous block copolymer membranes – J. Membrane Sci. 2006, 286, 144–152. DOI: 10.1016/j.memsci.2006.09.028

(119) Bailey, T. S.; Rzayev, J.; Hillmyer, M. A. – Routes to Alkene and Epoxide Functionalized Nanoporous Materials from Poly(styrene–b–isoprene–b–lactide) Triblock Copolymers – Macromolecules 2006, 39, 8772–8781.


DOI: 10.1021/ma061892b

(118) Li, Z.; Hillmyer, M. A.; Lodge, T. P. – Morphologies of Multicompartment Micelles Formed by ABC Miktoarm Star Terpolymers – Langmuir 2006, 22, 9409–9417. DOI: 10.1021/la0620051

(117) Cooney, D. T.; Hillmyer, M. A.; Cussler, E. L.; Moggridge, G. D. – Diffusion in nanoporous materials made from block copolymers – Cryst. Rev. 2006, 12, 13–24. DOI: 10.1080/08893110600688980

(116) Edmonds, W. F.; Li, Z.; Hillmyer, M. A. Lodge, T. P. – Disk Micelles from Nonionic Coil–Coil Diblock Copolymers – Macromolecules 2006, 39, 4526–4530. DOI: 10.1021/ma060633j

(115) Zupancich, J. A.; Bates, F. S.; Hillmyer, M. A. – Aqueous Dispersions of Poly(ethylene oxide)–b–poly(γ–methyl–ε–caprolactone) Block Copolymers – Macromolecules 2006, 39, 4286–4288. DOI: 10.1021/ma060642s

(114) Li, Z.; Hillmyer, M. A.; Lodge, T. P. – Laterally Nanostructured Vesicles, Polygonal Bilayer Sheets, and Segmented Wormlike Micelles – Nano Letters 2006, 6, 1245–1249. DOI: 10.1021/nl0608700

(113) Guo, S.; Rzayev, J.; Bailey, T. S.; Zalusky, A. S.; Olayo–Valles, R.; Hillmyer, M. A. – Nanopore and nanobushing arrays from ABC triblock thin films containing two etchable blocks – Chem. Mater. 2006, 18, 1719–1721.
DOI: 10.1021/cm052694m

(112) Anderson, K. A.; Hillmyer, M. A. – Melt Preparation and Nucleation Efficiency of Polylactide Stereocomplex Crystallites – Polymer 2006, 47, 2030–2035. DOI: 10.1016/j.polymer.2006.01.062

(111) Breyfogle, L. E.; Williams, C. K.; Young, V. G.; Hillmyer, M. A.; Tolman, W. B. – Comparison of Structurally Analogous Zn2, Co2, and Mg2 Catalysts for the Polymerization of Cyclic Esters – Dalton Trans. 2006, 928–936.
DOI: 10.1039/B507014G

(110) Li, Z.; Hillmyer, M. A.; Lodge, T. P. – Control of Structure in Multicompartment Micelles by Blending µ–ABC Star Terpolymers with AB Diblock Copolymers – Macromolecules 2006, 39, 765–771. DOI: 10.1021/ma052199b

(109) Koo, C. M.; Hillmyer, M. A.; Bates, F. S. – Structure and Properties of Semicrystalline–Rubbery Multiblock Copolymers – Macromolecules 2006, 39, 667–677. DOI: 10.1021/ma051098a

(108) Mao, H.; Hillmyer, M. A. – Macroscopic samples of polystyrene with ordered three–dimensional nanochannels – Soft Matter 2006, 2, 57–59. DOI: 10.1039/B513958A

(107) Lodge, T. P.; Rasdal, A.; Li, Z.; Hillmyer, M. A. – Simultaneous, Segregated Storage of Two Agents in a Multicompartment Micelle – J. Am. Chem. Soc. 2005, 127, 17608–17609. DOI: 10.1021/ja056841t

(106) Hillmyer, M. A. – Nanoporous Materials from Block Copolymer Precursors – Adv. Polym. Sci. 2005, 190, 137–181. DOI: 10.1007/12_002

(105) Olayo–Valles, R.; Guo, S.; Lund, M. S.; Leighton, C.; Hillmyer, M. A. – Perpendicular Domain Orientation in Thin Films of Polystyrene–Polylactide Diblock Copolymers – Macromolecules 2005, 38, 10101–10108.
DOI: 10.1021/ma0509006

(104) Jensen, T. R.; Schaller, C. P.; Hillmyer, M. A.; Tolman, W. B. – Zinc N–heterocyclic carbene complexes and their polymerization of D,L–lactide – J. Organomet. Chem. 2005, 690, 5881–5891.


DOI: 10.1016/j.jorganchem.2005.07.070

(103) Zhu, S.; Edmonds, W. F.; Hillmyer, M. A.; Lodge, T. P. – Synthesis and Self–Assembly of Highly Incompatible Polybutadiene–Poly(hexafluoropropylene oxide) Diblock Copolymers – J. Polym. Sci. Polym. Phys. 2005, 43, 3685–3694. DOI: 10.1002/polb.20621

(102) Lynd, N. A.; Hillmyer, M. A. – The Influence of Polydispersity on the Self–Assembly of Diblock Copolymers – Macromolecules 2005, 38, 8803–8810. DOI: 10.1021/ma051025r

(101) Rzayev, J.; Hillmyer, M. A. – Nanochannel Array Plastics with Tailored Surface Chemistry – J. Am. Chem. Soc. 2005, 127, 13373–13379. DOI: 10.1021/ja053731d

(100) Mahanthappa, M. K.; Bates, F. S.; Hillmyer, M. A. – Synthesis of ABA Triblock Copolymers by a Tandem ROMP–RAFT Strategy – Macromolecules 2005, 38, 7890–7894. DOI: 10.1021/ma051535l

(99) Bae, C.; Hartwig, J. F.; Chung, H.; Harris, N. K.; Switek, K. A.; Hillmyer, M. A. – Regiospecific conversion of a linear low–density polyethylene to a material with boryl, hydroxyl, amino, and formyl groups at the termini of side chains – Angew. Chem. Int. Ed. 2005, 44, 2–6. DOI: 10.1002/anie.200501837

(98) Lape, N. K.; Mao, H.; Camper, D.; Hillmyer, M. A.; Cussler, E. L. – Barrier Membranes of Self–Assembled Lamellar Poly(Lactide–Isoprene–Lactide) Triblock Copolymers – J. Membrane Sci. 2005, 259, 1–9.
DOI: 10.1016/j.memsci.2004.11.035

(97) Koo, C. M.; Wu, L.; Lim. L. S.; Mahanthappa, M. K.; Hillmyer, M. A.; Bates, F. S. – Microstructure and Mechanical Properties of Semicrystalline–Rubbery–Semicrystalline Triblock Copolymers – Macromolecules 2005, 38, 6090–6098. DOI: 10.1021/ma0501794

(96) Zhang, C.; Hillmyer, M. A.; Tolman, W. B. – Catalytic Polymerization of a Cyclic Ester Derived from a "Cool" Natural Precursor – Biomacromolecules 2005, 6, 2091–2095. DOI: 10.1021/bm050076t

(95) Mao, H.; Hillmyer, M. A. – Nanoporous Polystyrene by Chemical Etching of Poly(ethylene oxide) from Ordered Block Copolymers – Macromolecules 2005, 38, 4038–4039. DOI: 10.1021/ma050008z

(94) Boaen, N. K.; Hillmyer, M. A. – Postpolymerization Functionalization of Polyolefins – Chem. Soc. Rev. 2005, 34, 267–275. DOI: 10.1039/b311405h

(93) Ha, J.–M.; Hillmyer, M. A.; Ward, M. D. – Thermotropic Properties of Organic Nanocrystals Embedded in Ultrasmall Crystallization Chambers – J. Phys. Chem. B. 2005, 109, 1392–1399. DOI: 10.1021/jp045488v

(92) Bae, C.; Hartwig, J. F.; Boaen Harris, N. K.; Long, R. O.; Anderson, K. A.; Hillmyer, M. A. – Catalytic Hydroxylation of Polypropylenes – J. Am. Chem. Soc. 2005, 127, 767–776. DOI: 10.1021/ja044440s

(91) Rzayev, J.; Hillmyer, M. A. – Nanoporous polystyrene containing hydrophilic pores from an ABC triblock copolymer precursor – Macromolecules 2005, 38, 3–5. DOI: 10.1021/ma047870b

(90) Mao, H.; Arrechea, P. L.; Bailey, T. S.; Johnson, B. J. S.; Hillmyer, M. A. – Control of pore hydrophilicity in ordered nanoporous polystyrene using an AB/AC block copolymer blending strategy – Faraday Disc. 2005, 128, 149–162. DOI: 10.1039/B403217A

(89) Lodge, T. P.; Bang, J.; Li, Z.; Hillmyer, M. A.; Talmon, Y. – Strategies for controlling intra– and intermicellar packing in block copolymer solutions: Illustrating the flexibility of the self–assembly toolbox – Faraday Discuss. 2005, 128, 1–12. DOI: 10.1039/b412755m

(88) Trammell, B. C.; Ma, L.; Luo, H.; Hillmyer, M. A.; Carr, P. W. – The Synthesis and Characterization of a Hypercrosslinked Surface–Confined Ultra–Stable Silica–Based Stationary Phases – J. Chrom. A 2004, 1060, 61–76.
DOI: 10.1016/j.chroma.2004.07.075

(87) Li, Z.; Hillmyer, M. A.; Lodge, T. P. – Synthesis and Characterization of Triptych µ–ABC Star Triblock Copolymers – Macromolecules 2004, 37, 8933–8940. DOI: 10.1021/ma048607d

(86) Anderson, K. A.; Hillmyer, M. A. – The influence of block copolymer microstructure on the toughness of compatibilized polylactide/polyethylene blends – Polymer 2004, 45, 8809–8823.
DOI: 10.1016/j.polymer.2004.10.047

(85) Zhang, D.; Hillmyer, M. A.; Tolman, W. B. – A New Synthetic Route to Poly[3–hydroxypropionic acid] (P[3–HP]): Ring–opening Polymerization of 3–HP Macrocyclic Esters – Macromolecules 2004, 37, 8198–8200.


DOI: 10.1021/ma048092q

(84) Jensen, T. R.; Breyfogle, L. E.; Hillmyer, M. A.; Tolman, W. B. – Stereoelective Polymerization of D,L–Lactide Using N–Heterocyclic Carbene Based Compounds – Chem. Comm. 2004, 2504–2505. DOI: 10.1039/B405362A

(83) Li, Z.; Kesselman, E.; Talmon, Y.; Hillmyer, M. A.; Lodge, T. P. – Multicompartment Micelles from ABC Triblock Copolymer Miktoarm Stars – Science 2004, 306, 98–101. DOI: 10.1126/science.1103350

(82) Olayo–Valles R.; Lund M. S.; Leighton, C.; Hillmyer, M. A. – Large area nanolithographic templates by selective etching of chemically stained block copolymer thin films – J. Mater. Chem. 2004, 14, 2729–2731.


DOI: 10.1039/B408639B

(81) Lodge, T. P.; Hillmyer, M. A.; Zhou, Z. – Access to the Superstrong Segregation Regime with Nonionic Block ABC Copolymers – Macromolecules 2004, 37, 6680–6682. DOI: 10.1021/ma048708b

(80) Switek, K. A.; Bates, F. S.; Hillmyer, M. A. – Star Polymer Synthesis Using Hexafluoropropylene Oxide as an Efficient Multifunctional Coupling Agent – Macromolecules 2004, 37, 6355–6361. DOI: 10.1021/ma035936h

(79) Lim, L. S.; Harada, T.; Hillmyer, M. A.; Bates, F. S. – High Strength Polyolefin Block Copolymers – Macromolecules 2004, 37, 5847–5850. DOI: 10.1021/ma048898q

(78) Hillmyer, M. A.; Schmuhl, N. W.; Lodge, T. P. – Fluorinated Amphiphilic Block Copolymers: Combining Anionic Polymerization and Selective Polymer Modification – Macromol. Symp. 2004, 215, 51–56.
DOI: 10.1002/masy.200451105

(77) Schreck, K. M.; Hillmyer, M. A. – Controlled polymerization of –methyl––pentyl––propiolactone by a discrete zinc alkoxide complex – Tetrahedron 2004, 60, 7177–7185. DOI: 10.1016/j.tet.2004.06.101

(76) Johnson, B. J. S.; Wolf, J. H.; Zalusky, A. S.; Hillmyer, M. A. – Template Syntheses of Polypyrrole Nanowires and CdS Nanoparticles in Porous Polymer Monoliths – Chem. Mater. 2004, 16, 2909–2917.
DOI: 10.1021/cm0350075


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