Marc Andrew Hillmyer



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(75) Zhang, D.; Xu, J.; Alcazar–Roman, L.; Greenman, L.; Cramer, C. J.; Hillmyer, M. A.; Tolman, W. B. – Isotactic Polymers with Alternating Lactic Acid and Oxetane Subunits from the Endoentropic Polymerization of a 14–membered Ring – Macromolecules 2004, 37, 5274–5281. DOI: 10.1021/ma049571s

(74) Cavicchi, K. A.; Zalusky, A. S.; Hillmyer, M. A.; Lodge, T. P. – An Ordered Nanoporous Monolith From an Elastomeric Crosslinked Block Copolymer Precursor – Macromol. Rapid Commun. 2004, 25, 704–709.


DOI: 10.1002/marc.200300245

(73) Ha, J. –M.; Wolf, J. H.; Hillmyer, M. A.; Ward, M. D. – Polymorph Selectivity under Nanoscopic Confinement – J. Am. Chem. Soc. 2004, 126, 3382–3383. DOI: 10.1021/ja049724r

(72) Anderson, K. S.; Hillmyer, M. A. – Melt Chain Dimensions of Polylactide – Macromolecules 2004, 37, 1857–1862. DOI: 10.1021/ma0357523

(71) Zhang, K.; Wang, Y.; Hillmyer, M. A.; Francis, L. F. – Processing and Properties of Porous Poly(L–lactide)/Bioactive Glass Composites – Biomaterials 2004, 25, 2489–2500. DOI: 10.1016/j.biomaterials.2003.09.033

(70) Davidock, D. A.; Hillmyer, M. A.; Lodge, T. P. – Mapping Large Regions of Diblock Copolymer Phase Space by Selective Chemical Modification – Macromolecules 2004, 37, 397–407. DOI: 10.1021/ma035248y

(69) Radhakrishnan, K.; Switek, K. A.; Hillmyer, M. A. – Synthesis of Semifluorinated Block Copolymers by Atom Transfer Radical Polymerization – J. Polym. Sci., Part A Polym. Chem. 2004, 42, 853–861. DOI: 10.1002/pola.11023

(68) Boaen, N. K.; Hillmyer, M. A. – Selective and Mild Oxyfunctionalization of Model Polyolefins – Macromolecules 2003, 36, 7027–7034. [Correction 2003, 36, 8906] DOI: 10.1021/ma0347621

(67) Williams, C.K.; Breyfogle, L. E.; Choi, S. K.; Nam, W. W.; Young, V. G.; Hillmyer, M. A.; Tolman, W. B. – A Highly Active Zinc Catalyst for the Controlled Polymerization of Lactide – J. Am. Chem. Soc. 2003, 125, 11350–11359. DOI: 10.1021/ja0359512

(66) Trammell, B. C.; Ma, L.; Luo, H.; Hillmyer, M. A.; Carr, P. W. – An Ultra Acid Stable Reversed Stationary Phase – J. Am. Chem. Soc. 2003, 125, 10504–10505. DOI: 10.1021/ja036339d

(65) Zhou, Z.; Li, Z.; Ren, Y.; Hillmyer, M. A.; Lodge, T. P. – Micellar Shape Change and Internal Segregation Induced by Chemical Modification of a Triptych Block Copolymer Surfactant – J. Am. Chem. Soc. 2003, 125, 10182–10183. DOI: 10.1021/ja036551h

(64) Wolf, J. H.; Hillmyer, M. A. – Ordered Nanoporous Polycyclohexylethylene – Langmuir 2003, 19, 6553–6560.
DOI: 10.1021/la0341862

(63) Anderson, K. S.; Lim, S. H.; Hillmyer, M. A. – Toughening of Polylactide by Melt Blending with Linear Low–Density Polyethylene – J. Appl. Polym. Sci. 2003, 89, 3757–3768. DOI: 10.1002/app.12462

(62) Alcazar–Roman, L. M.; O’Keefe, B. J.; Hillmyer, M. A.; Tolman, W. B. – Electronic Influence of Ligand Substituents on the Rate of Polymerization of –Caprolactone by Single–Site Aluminum Alkoxide Catalysts J. Chem. Soc., Dalton Trans. 2003, 3082–3087. DOI: 10.1039/B303760F

(61) Davidock, D. A.; Hillmyer, M. A.; Lodge, T. P. – Persistence of the Gyroid Morphology at Strong Segregation in Diblock Copolymers – Macromolecules 2003, 36, 4682–4685. DOI: 10.1021/ma034364y

(60) Frick, E. M.; Zalusky, A. S.; Hillmyer, M. A. – Characterization of polylactide–b–polyisoprene–b–polylactide thermoplastic elastomers – Biomacromolecules 2003, 4, 216–223. DOI: 10.1021/bm025628b

(59) Hahn, S. F.; Hillmyer, M. A. – High Glass Transition Temperature Polyolefins by the Catalytic Hydrogenation of Polyindene – Macromolecules 2003, 36, 71–76. DOI: 10.1021/ma021084u

(58) Zalusky, A. S.; Olayo–Valles, R.; Wolf, J. H.; Hillmyer, M. A. – Ordered Nanoporous Polymers from Polystyrene–Polylactide Block Copolymers – J. Am. Chem. Soc. 2002, 124, 12761–12773. DOI: 10.1021/ja0278584

(57) Zell, M. T.; Padden, B. E.; Paterick, A. J.; Thakur, K. A. M.; Kean, R. T.; Hillmyer, M. A.; Munson, E. J. – Unambiguous Determination of the 13C and 1H NMR Stereosequence Assignments of Polylactide Using High–Resolution Solution NMR Spectroscopy – Macromolecules 2002, 35, 7700–7707. DOI: 10.1021/ma0204148

(56) Almdal, K.; Hillmyer, M. A.; Bates, F. S. – Influence of Conformational Asymmetry on Polymer–Polymer Interactions: An Entropic or Enthalpic Effect? – Macromolecules 2002, 35, 7685–7691. DOI: 10.1021/ma020148y

(55) Kumar, A.; Gross, R. A.; Wang, Y.; Hillmyer, M. A. – Recognition by Lipase of –Hydroxyl Macroinitiators for Diblock Copolymer Synthesis – Macromolecules 2002, 35, 7606–7611. DOI: 10.1021/ma020060k

(54) Trammell, B. C.; Ma, L.; Luo, H.; Jin, D.; Hillmyer, M. A.; Carr, P. W. – Highly Cross-linked Self–Assembled Monolayer Stationary Phases: An Approach to Greatly Enhancing the Low pH Stability of Silica–Based Stationary Phases – Anal. Chem. 2002, 74, 4634–4639. DOI: 10.1021/ac020206d

(53) Williams, C. K.; Brooks, N. R.; Hillmyer, M. A.; Tolman, W. B. – Metalloenzyme inspired dizinc catalyst for the polymerisation of lactide – J. Chem. Soc., Chem. Comm. 2002, 18, 2132–2133. DOI: 10.1039/B206437E

(52) Schmidt, S. C.; Hillmyer, M. A. – Morphological Behavior of Model Poly(ethylene–alt–propylene)–b–Polylactide Block Copolymers – J. Polym. Sci. Part B: Polym. Phys. 2002, 40, 2364–2376. DOI: 10.1002/polb.10291

(51) McHugh, M. A.; Park, I. –H.; Reisinger, J. J.; Ren, Y.; Lodge, T. P.; Hillmyer, M. A. – Solubility of CF2–modified polybutadiene and polyisoprene in supercritical carbon dioxide – Macromolecules 2002, 35, 4653–4657.


DOI: 10.1021/ma012170h

(50) Ren, Y.; Lodge, T. P.; Hillmyer, M. A. – The Effect of Selective Perfluoroalkylation the Segregation Strength of Polystyrene–1,2–Polybutadiene Block Copolymers – Macromolecules 2002, 35, 3889–3894.


DOI: 10.1021/ma011958x

(49) Reisinger, J. J.; Hillmyer, M. A. – Synthesis of Fluorinated Polymers By Chemical Modification – Prog. Polym. Sci. 2002, 27, 971–1005. DOI: 10.1016/S0079-6700(02)00004-7

(48) O’Keefe, B. J.; Breyfogle, L. E.; Hillmyer, M. A.; Tolman, W. B. – Mechanistic Comparison of Cyclic Ester Polymerizations by Novel Iron(III)–Alkoxide Complexes: Single vs. Multiple Site Catalysts – J. Am. Chem. Soc. 2002, 124, 4384–4393. DOI: 10.1021/ja012689t

(47) Kondo, Y.; Garcia–Cuadrado, D.; Hartwig, J. F.; Boaen, N. K.; Wagner, N. B.; Hillmyer, M. A. – Rhodium–Catalyzed Regiospecific Functionalization of Polyolefins in the Melt – J. Am. Chem. Soc. 2002, 124, 1164–1165.


DOI: 10.1021/ja016763j

(46) Aubrecht, K. B.; Hillmyer, M. A.; Tolman, W. B. – Polymerization of Lactide by Monomeric Sn(II) Alkoxide Complexes – Macromolecules 2002, 35, 644–650. DOI: 10.1021/ma011873w

(45) Ness, J. S.; Brodil, J. C.; Bates, F. S.; Hahn, S. F.; Hucul D. A.; Hillmyer, M. A. – Molecular Weight effects in the Hydrogenation of Model Polystyrenes Using Platinum Supported on Wide Pore Silica – Macromolecules 2002, 35, 602–609. DOI: 10.1021/ma010960l

(44) Bechtold, K.; Hillmyer, M. A.; Tolman, W. B. – The Perfectly Alternating Copolymer of Lactic Acid and Ethylene Oxide as a Plasticizing Agent for Polylactide – Macromolecules 2001, 34, 8641–8648.


DOI: 10.1021/ma0114887

(43) Li, M.; Carter, B.; Hillmyer, M. A.; Gerberich, W. W. – Adhesion of Polymer–Inorganic Interfaces by Nanoindentation – J. Mat. Res. 2001, 16, 3378–3388. DOI: 10.1557/JMR.2001.0466

(42) O’Keefe, B. J.; Hillmyer, M. A.; Tolman, W. B. – Polymerization of lactide and related cyclic esters by discrete metal complexes – J. Chem. Soc., Dalton Trans. 2001, 2215–2224. DOI: 10.1039/B104197P

(41) Wang, Y.; Hillmyer, M. A. – Polyethylene–Poly(l–Lactide) Diblock Copolymers: Synthesis and Compatibilization of Poly(l–Lactide)/Polyethylene Blends – J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 2755–2766. DOI: 10.1002/pola.1254

(40) Ren, Y.; Lodge, T. P.; Hillmyer, M. A. – A Simple and Mild Route to Highly Fluorinated Model Polymers – Macromolecules 2001, 34, 4780–4787. DOI: 10.1021/ma010229e

(39) Trammel, B.; Hillmyer, M. A.; Carr, P. W. – A Study of the Lewis Acid–Base Interactions of Vinylphosphonic Acid Modified Polybutadiene–coated Zirconia – Anal. Chem. 2001, 73, 3323–3331. DOI: 10.1021/ac010032k

(38) Zalusky, A. S.; Olayo–Valles, R.; Taylor, C. J.; Hillmyer, M. A. – Mesoporous Polystyrene Monoliths – J. Am. Chem. Soc. 2001, 123, 1519–1520. DOI: 10.1021/ja003936g

(37) O’Keefe, B. J.; Monnier, S. M.; Hillmyer, M. A.; Tolman, W. B. – Rapid and Controlled Polymerization of Lactide by Structurally Characterized Ferric Alkoxides – J. Am. Chem. Soc. 2001, 123, 339–340.
DOI: 10.1021/ja003537l

(36) Aubrecht, K. B.; Chang, K.; Hillmyer, M. A.; Tolman, W. B. – Lactide Polymerization Activity of Alkoxide, Phenoxide, and Amide Derivatives of Yttrium(III) Arylamidinates – J. Polym. Sci. Polym. Chem. 2001, 39, 284–293.


DOI: 10.1002/1099-0518(20010115)39:2<284::AID-POLA40>3.0.CO;2-C

(35) Schmidt, S. C.; Hillmyer, M. A. – Polylactide Sterocomplex Crystallites as Nucleating Agents for Isotactic Polylactide – J. Polym. Sci., Part B: Polym. Phys. 2001, 39, 300–313.


DOI: 10.1002/1099-0488(20010201)39:3<300::AID-POLB1002>3.0.CO;2-M

(34) Frick, E. M.; Hillmyer, M. A. – Synthesis and Characterization of Polylactide–b–Polyisoprene–b–Polylactide Triblock Copolymers: New Thermoplastic Elastomers Containing Biodegradable Segments – Macromol. Rapid Commun. 2000, 21, 1317–1322. DOI: 10.1002/1521-3927(20001201)21:18<1317::AID-MARC1317>3.0.CO;2-B

(33) Wang, Y.; Hillmyer, M. A. – The Synthesis of Polybutadiene–Polylactide Diblock Copolymers using Aluminum Alkoxide Macroinitiators. Kinetics and Mechanism – Macromolecules 2000, 33, 7395–7403.
DOI: 10.1021/ma0007177

(32) Chamberlain, B. M.; Jazdzewski, B. A.; Pink M.; Hillmyer, M. A.; Tolman, W. B. – The Controlled Polymerization of D, L–Lactide and –Caprolactone by Structurally Well–Defined Alkoxo–Bridged Di– and Triyttrium(III) Complexes – Macromolecules 2000, 33, 3970–3977. DOI: 10.1021/ma0000834

(31) Ren, Y.; Lodge, T. P.; Hillmyer, M. A. – Synthesis, Characterization and Interaction Strengths of Difluorocarbene–Modified Polystyrene–Polyisoprene Block Copolymers – Macromolecules 2000, 33, 866–876.
DOI: 10.1021/ma9917085

(30) Shefelbine, T. A.; Vigild, M. E.; Matsen, M. W.; Hajduk, D. A.; Hillmyer, M. A.; Cussler, E. L.; Bates, F. S. – Core–Shell Gyroid Morphology in a Poly(isoprene–block–styrene–block–dimethylsiloxane) Triblock Copolymer – J. Am. Chem. Soc. 1999, 121, 8457–8465. DOI: 10.1021/ja991442h

(29) Cramer, C. J.; Hillmyer, M. A. – Perfluorocarbenes Produced by Thermal Cracking. Barriers to Generation and Rearrangement – J. Org. Chem. 1999, 64, 4850–4859. DOI: 10.1021/jo990248a

(28) Schmidt, S. C.; Hillmyer, M. A. – Synthesis and Characterization of Model Polyisoprene–Polylactide Diblock Copolymers – Macromolecules 1999, 32, 4794–4801. DOI: 10.1021/ma9900277

(27) Hillmyer, M. A.; Almdal, K.; Lodge, T. P.; Maurer, W. W.; Bates, F. S. – Model Bicontinuous Microemulsions in Ternary Homopolymer/Block Copolymer Blends – J. Phys. Chem. B. 1999, 103, 4814–4824. DOI: 10.1021/jp990089z

(26) Chamberlin, B. M.; Sun, Y.; Hagadorn, J. R.; Hemmesch, E. W.; Young, V. G.; Pink, M.; Hillmyer, M. A.; Tolman, W. B. – Discrete Yttrium(III) Complexes as Lactide Polymerization Catalysts – Macromolecules 1999, 32, 2400–2402. DOI: 10.1021/ma990005k

(25) Zell, M. T.; Padden, B. E.; Paterick, A. J.; Hillmyer, M. A.; Kean, R. T.; Thakur, K. A. M.; Munson, E. J. – Direct Observation of Stereodefect Sites in Semicrystalline Poly(lactide) Using 13C Solid–State NMR – J. Am. Chem. Soc. 1998, 120, 12672–12673. DOI: 10.1021/ja981773e

(24) Lipic, P. M.; Bates, F. S.; Hillmyer, M. A. – Nanostructured Thermosets Templated by Amphiphilic Block Copolymers – J. Am. Chem. Soc. 1998, 120, 8963–8970. DOI: 10.1021/ja981544s

(23) Ren, Y.; Lodge, T. P.; Hillmyer, M. A. – A New Class of Fluorinated Polymers by a Mild, Selective, and Quantitative Fluorination – J. Am. Chem. Soc. 1998, 120, 6830–6831. [Correction 1998, 120, 9116]
DOI: 10.1021/ja981316y

(22) Hajduk, D. A.; Kossuth, M. B.; Hillmyer, M. A.; Bates, F. S. – Complex Phase Behavior in Aqueous Solutions of Poly(ethylene oxide)–Poly(ethylethylene) (PEO–PEE) Block Copolymers – J. Phys. Chem. B. 1998, 102, 4269–4276.


DOI: 10.1021/jp973323z

(21) Hamersky, M. W.; Hillmyer, M. A.; Tirrell, M.; Bates, F. S.; Lodge, T. P. – Block Copolymer Self–Diffusion in the Gyroid and Cylinder Morphologies – Macromolecules 1998, 31, 5363–5370. DOI: 10.1021/ma971476e

(20) Hajduk, D. A.; Ho, R.–M.; Hillmyer, M. A.; Bates, F. S.; Almdal, K. – Transition Mechanisms for Complex Ordered Phases in Block Copolymer Melts – J. Phys. Chem. B. 1998, 102, 1356–1363. DOI: 10.1021/jp972871+

(19) Bates, F. S.; Maurer, W. W.; Lipic, P. M.; Hillmyer, M. A.; Almdal, K.; Mortensen, K.; Fredrickson, G. H.; Lodge, T. P. – Polymeric Bicontinuous Microemulsions – Phys. Rev. Lett. 1997, 79, 849–852.


DOI: 10.1103/PhysRevLett.79.849

(18) Tepe, T.; Hillmyer, M. A.; Weimann, P. A.; Tirrell, M.; Bates, F. S.; Almdal, K.; Mortensen, K. – Influence of Shear on a Lamellar Triblock Copolymer Near the Order–Disorder Transition – J. Rheol. 1997, 41, 1147–1171.


DOI: 10.1122/1.550819

(17) Hajduk, D. A.; Takenouchi, H.; Hillmyer, M. A.; Bates, F. S.; Vigild, M. E.; Almdal, K. A. – Stability of the Perforated Layer (PL) Phase in Diblock Copolymer Melts – Macromolecules 1997, 30, 3788–3795.


DOI: 10.1021/ma961673y

(16) Weimann, P. A.; Jones, T. D.; Hillmyer, M. A.; Bates, F. S.; Londono, J. D.; Melnichenko, Y.; Wignall, G. D.; Almdal, K. – Phase Behavior of Isotactic Polypropylene–Poly(ethylene–ethylethylene) Random Copolymer Blends – Macromolecules 1997, 30, 3650–3657. DOI: 10.1021/ma961383h

(15) Hillmyer, M. A.; Bates, F. S. – Influence of Crystallinity on the Morphology of Poly(ethylene oxide) Containing Block Copolymers – Macromol. Symp. 1997, 117, 121–130. DOI: 10.1002/masy.19971170116

(14) Hillmyer, M. A.; Lipic, P. M.; Hajduk, D. A.; Almdal, K.; Bates, F. S. – Self–Assembly and Polymerization of Epoxy Resin–Amphiphilic Block Copolymer Nanocomposites – J. Am. Chem. Soc. 1997, 119, 2749–2750.


DOI: 10.1021/ja963622m

(13) Hillmyer, M. A.; Nguyen, S. T.; Grubbs, R. H. – Utility of a Ruthenium Metathesis Catalyst for the Preparation of End–Functionalized Polybutadiene – Macromolecules 1997, 30, 718–721. DOI: 10.1021/ma961316n

(12) Hillmyer, M. A.; Bates, F. S. – Synthesis and Characterization of Model Polyalkane–Poly(ethylene oxide) Block Copolymers – Macromolecules 1996, 29, 6994–7002. DOI: 10.1021/ma960774t

(11) Walba, D. M.; Keller, P.; Shao, R.; Clark, N. A.; Hillmyer, M. A.; Grubbs, R. H. – Main–Chain Ferroelectric Liquid Crystal Oligomers by Acyclic Diene Metathesis Polymerization – J. Am. Chem. Soc. 1996, 118, 2740–2741.


DOI: 10.1021/ja953779z

(10) Hillmyer, M. A.; Bates, F. S.; Ryan, A. J.; Almdal, K.; Mortensen, K.; Fairclough, J. P. – Complex Phase Behavior in Solvent–Free Nonionic Surfactants – Science 1996, 271, 976–978. DOI: 10.1126/science.271.5251.976

(9) Hillmyer, M. A.; Grubbs, R. H. – Chain Transfer in the Ring–Opening Metathesis Polymerization of Cyclooctadiene Using Discrete Metal Alkylidenes – Macromolecules 1995, 28, 8662–8667.
DOI: 10.1021/ma00129a027

(8) Fraser, C. F.; Hillmyer, M. A.; Gutierrez, E.; Grubbs, R. H. – Degradable Cyclooctadiene/Acetal Copolymers: Versatile Precursors to 1,4–Hydroxytelechelic Polybutadiene and Hydroxytelechelic Polyethylene – Macromolecules 1995, 28, 7256–7261. DOI: 10.1021/ma00125a031

(7) Hillmyer, M. A.; Laredo, W. R.; Grubbs, R. H. – The Ring–Opening Metathesis Polymerization of Functionalized Cyclooctenes by a Ruthenium–Based Metathesis Catalyst – Macromolecules 1995, 28, 6311–6316.
DOI: 10.1021/ma00122a043

(6) Hillmyer, M. A.; Benedicto, A. D.; Nguyen, S. T.; Wu, Z.; Grubbs, R. H. – Ring–Opening Metathesis Copolymerization Employing Ruthenium–Based Methathesis Catalysts – Macromol. Symp. 1995, 89, 411–419.


DOI: 10.1002/masy.19950890138

(5) Hillmyer, M. A.; Grubbs, R. H. – Preparation of Hydroxytelechelic Polybutadiene via Ring–Opening Metathesis Polymerization Employing a Well–Defined Metathesis Catalyst – Macromolecules 1993, 26, 872–874.


DOI: 10.1021/ma00056a051

(4) Tan, L. –C.; Pangi, R.; Kabalka, G. W.; Hillmyer, M. A.; Woosley, J. – The Macrocyclization Reaction of Terminal Dibromoalkanes with Sulfide on Alumina – Tetrahedron Lett. 1992, 33, 7709–7712.


DOI: 10.1016/0040-4039(93)88023-C

(3) Hillmyer, M. A.; Lepetit, C.; McGrath, D. V.; Novak, B. M.; Grubbs, R. H. – Aqueous Ring–Opening Metathesis Polymerization of Carboximide–Functionalized 7–Oxanorbornenes – Macromolecules 1992, 25, 3345–3350.


DOI: 10.1021/ma00039a004

(2) Wagener, K. B.; Nel J. G.; Duttweiler, R. P.; Hillmyer, M. A.; Boncella, J. M.; Konzelman, J.; Smith, D. W.; Puts, R.; Willoughby, L. – Metathesis Polycondensation Chemistry as a Route to Unsaturated Elastomers – Rubber Chem. and Tech. 1991, 64, 83–95. DOI: 10.5254/1.3538543

(1) Wagener, K. B.; Boncella, J. M.; Nel, J. G.; Duttweiler, R. P.; Hillmyer, M. A. – The Key to Successful Acyclic Diene Metathesis Polymerization Chemistry – Makromol. Chem. 1990, 191, 365–374.
DOI: 10.1002/macp.1990.021910210

other publications

(16) Hillmyer, M A. – The promise of plastics from plants (A Perspective) – Science 2017, 358, 868–870.

(15) Schneiderman, D. K.; Hill, E. M.; Hillmyer, M. A. – Aliphatic Polyester Copolymers and Terpolymers for TPE applications – Extended abstract for the Society of Plastics Engineers Topical Conference on Thermoplastic Elastomers September 2016 in Akron Ohio.

(14) Rowan, S. J.; Barner-Kowollik, C.; Klumperman, B.; Gaspard, P.; Grubbs, R. B.; Hillmyer, M. A.; Hutchings, L. R.; Mahanthappa, M. K.; Maotsou; D.; O’Reilly, R. K.; Ouchi, M.; Sawamoto, M. – Discussion on “Aperiodic Copolymers” – ACS Macro Lett. 2016, 5, 1–3. DOI: 10.1021/acsmacrolett.5b00758

(13) Hillmyer, M. A. – “Polymer Synthesis” a chapter in Comprehensive Polymer Science (second edition), edited by Kris Matyjaszewski and Martin Möller, 2011 Elsevier.

(12) Jackson, E. A.; Hillmyer, M. A. – Nanoporous Membranes Derived from Block Copolymers: From Drug Delivery to Water Filtration – ACS Nano 2010, 4, 3548–3553. DOI: 10.1021/nn1014006

(11) Robertson, M. L; Hillmyer, M. A.; Mortamet, A. -C.; Ryan, A. J. – Biorenewable Multiphase Polymers – MRS Bulletin 2010, 35, 194–200. DOI: 10.1557/mrs2010.651

(10) Coates, G. W.; Hillmyer, M. A. – A Virtual Issue of Macromolecules: Polymers from Renewable Resources – Macromolecules 2009, 42, 7987–7989. DOI: 10.1021/ma902107w

(9) Williams, C. K.; Hillmyer, M. A. – Polymers from renewable resources (A perspective) – Polymer Reviews 2008, 48, 1–10. DOI: 10.1080/15583720701834133

(8) Hillmyer, M. A. – Polydisperse block copolymers: Don’t throw them away (A viewpoint) – J. Polym. Sci. Polym. Phys. 2007, 45, 3249–3251. DOI: 10.1002/polb.21323

(7) Hillmyer, M. A. – Micelles Made to Order (A perspective) – Science 2007, 317, 604–605.
DOI: 10.1126/science.1144899

(6) Bielawski, C. W.; Hillmyer, M. A. – Telechelic Polymers from Olefin Metathesis – Olefin Metathesis Handbook Grubbs, R. H. Ed. Wiley–VCH: Weinheim, Germany 2003. DOI: 10.1002/9783527619481.ch37

(5) Hillmyer, M. A.; Lodge, T. P. – Synthesis and Self–Assembly of Fluorinated Block Copolymers (A highlight)– J. Polym. Sci. Polym. Chem. 2002, 40, 1. DOI: 10.1002/pola.10074

(4) Hillmyer, M. A.; Moore, J. S. – Editorial in materials for the 21st century special issue – J. Phys. Org. Chem. 2000, 13, 765. DOI: 10.1002/1099-1395(200012)13:12<765::AID-POC336>3.0.CO;2-6

(3) Hillmyer, M. A. – Review of “Polymer Synthesis: An Introduction” by M.P. Stevens – AIChE Journal 2000, 46, 1900.

(2) Hillmyer, M. A. – Block Copolymer Synthesis – In Encyclopedia of Materials: Science and Technology Buschow, K. H.; Cahn, R. W.; Flemings, M. C.; Ilschner, B.; Kramer, E. J.; Mahajan, S. Eds.; Elsevier Science: NewYork, NY 2001. (Also published in Current Opinion in Solid State & Materials Science 1999, 4, 559.) DOI: 10.1016/S1359-0286(00)00006-1

(1) Hillmyer, M. A. – Choosing a High Pressure Reaction Vessel – Today’s Chemist at Work 1999, 8, 21.

books

(1) Michael S. Silverstein, Neil R. Cameron, Marc A. Hillmyer Eds. – “Porous Polymers” – Wiley, 2011 (ISBN: 978-0470390849) DOI: 10.1002/9780470929445



patents issued

(17) Hillmyer, M. A.; Panthani, T. R.; Vanderlaan, M. E.; Schneiderman, D. K.; Mannion, A. M. R.; Batiste, D. C.; Macosko, C. W.; Wang, J. Z.; Bates, F. S. Recovery of monomer from polyurethane materials by depolymerization. U.S. 9,815,808, November 14, 2017

(16) Tolman, W. B.; Hillmyer, M. A.; John, A.; Hogan, L. T. Catalytic ester decarbonylation. U.S. Patent 9,718,763, August 1, 2017

(15) Gallagher, J.; Reineke, T. R.; Hillmyer, M. A. Monomers, polymers, and articles containing the same from sugar derived compounds. U.S. Patent 9,505,778, November 26, 2016

(14) Hustad, P. D.; Trefonas, P.; Bates, F. S.; Hillmyer, M. A.; Kennemur, J. G. Polystyrene-polyacrylate block copolymers, methods of manufacture thereof and articles comprising the same. U.S. Patent 9,127,113, September 8, 2015

(13) Hillmyer, M. A.; Pitet, L.; Amendt, M. Nanoporous linear polyolefin linear polyolefin membranes and block copolymer precursors for the same. U.S. Patent 9,051,431, June 9, 2015

(12) Jing, F.; Hillmyer, M.A. Bifunctional lactide monomer derivative and polymers and materials prepared using the same. U.S. Patent 8,203,007, June 19, 2012.

(11) Connell, E.J.; Hillmyer, M.A.; Robertson, M.L. Polylactide composites and methods of producing the same. U.S. Patent 7,939,603, May 10, 2011.

(10) Connell, E.J.; Hillmyer, M.A.; Chang, K. Block copolymer modified vegetable oil and polymer blends and methods of making same. U.S. Patent 7,888,418, February 15, 2011.

(9) Varma, A.; Chaffin, K.A.; Bates, F.; Hillmyer, M.A.; Lim, L. Process for producing a hyper-elastic, high strength dilatation balloon made from multi-block copolymers. U.S. Patent 7,879,270, February 1, 2011.

(8) Zhang, D.; Tolman, W.B.; Hillmyer, M.A. Polymer synthesis from macrocycles. U.S. Patent 7,714,097, May 11, 2010.

(7) Carr, P.W.; Hillmyer, M.A.; Liu, H.; Luo, H.; Ma, L.; Trammell, B. Silica-based materials and methods. U.S. Patent 6,991,852, January 31, 2006.

(6) Boaen, N.K.; Hillmyer, M.A.; Hahn, S.F. Oxyfunctionalization of polyolefins. U.S. Patent 6,953,868, October 11, 2005.

(5) Woodson, C.S.; Hillmyer, M.A.; Grubbs, R.H.; Lodge, T.P.; Ren, Y. Fluorinated polymers and methods for their preparation. U.S. Patent 6,433,101, August 13, 2002.

(4) Grubbs, R.H.; Nguyen, S.T.; Hillmyer, M.A. Synthesis of telechelic polymers using ruthenium and osmium carbene complexes. U.S. Patent 5,880,231, March 9, 1999.

(3) Grubbs, R.H.; Nguyen, S.T.; Hillmyer, M.A. Romp of functionalized cyclic olefins using ruthenium and osmium carbene complexes. U.S. Patent 5,849,851, December 15, 1998.

(2) Wagener, K.B.; Boncella, J.M.; Duttweiler, R.P.; Hillmyer, M.A.; Nel, J.G. Polymerized dienes prepared by step propagation, condensation type polymerization of acyclic dienes. U.S. Patent 5,290,895, March 1, 1994.

(1) Wagener, K.B.; Boncella, J.M.; Duttweiler, R.P.; Hillmyer, M.A.; Nel, J.G. Method for polymerizing acyclic dienes. U.S. Patent 5,110,885, May 5, 1992.


invited lectures

Scientific Meetings

2019 High Polymer Research Group Conference – Pott Shrigley, England – April 2019


Membranes: From Molecules to Modules GRC – Colby Sawyer Coll. – New London, New Hampshire – August 2018

Nano-, Meso- & Microstructured Materials for Energy, Electronics & Biotech – Shenzhen, China – April 2018

253rd National ACS Meeting – New Orleans, LA – March 2018
252nd National ACS Meeting – Washington, DC – August 2017 (2 invited talks)

Polymer Gordon Conference – Mount Holyoake, Massachusetts – June 2017

12th Intl. Conf. on Advanced Polymers via Macromolecular Engineering (APME 2017) – Ghent, Belgium – May 2017

251st National ACS Meeting – San Francisco, California – April 2017

Fats and Oils as Renewable Feedstocks for the Chemical Industry – Karlsruhe, Germany – March 2017

APS 2017 March Meeting – New Orleans, Louisiana – March 2017

KAUST Research Conference – Jeddah, Saudia Arabia – February 2017

Intl. Conf. on Polymer Sci. & Tech. (MACRO2017) – Thiruvananthapuram, India – January 2017 (Plenary lecture)

International Conference on Advances in Functional Materials – Chennai, India – January 2017
ESPCI-Michelin Workshop – Paris, France – November 2016

Plastics Engineers 12th Topical Conference on Thermoplastic Elastomers – Akron, Ohio – September 2016

Warwick 2016 – Warwick, England – July 2016 (Plenary lecture)

2016 United States-Japan Polymer Symposium – Hokkaido, Japan – June 2016

8th Annual Triangle Soft Matter Workshop – Durham, North Carolina – May 2016 (Plenary lecture)

249th ACS National Meeting – San Diego, California – March 2016 (2 invited talks)

Smart Coatings 2016 – Orlando, Florida – February 2016 (Plenary lecture)
Pacifichem 2015 Meeting – Honolulu, Hawaii – December 2015 (2 invited talks)

14th Pacific Polymer Conference – Kauai, Hawaii – December 2015

1st Annual Green Materials Symposium (Plenary lecture) – London, England – December 2015

248th ACS National Meeting – Denver, Colorado – March 2015 (3 invited talks)


10th SPSJ International Polymer Conference Tsukuba, Japan – December 2014
247th ACS National Meeting – San Francisco, California – August 2014 (2 invited talks)

Canadian High Polymer Forum – Gananoque, Canada – July 2014 (Keynote)

9th Annual GC3 Innovators Roundtable – St. Paul, Minnesota – May 2014 (Keynote)

Programmable Materials Workshop, University of Illinois – Urbana Champaign, Illinois – May 2014

246th ACS National Meeting – Dallas, Texas – March 2014

Pittcon 2014 – Chicago, Illinois – March 2014


245th ACS National Meeting – Indianapolis, IN – September 2013 (3 invited talks)

2013 Dutch Polymer Days Conference – Lunteren, The Netherlands – March 2013 (Plenary)


2012 Polymer Physics Gordon Conference – Mount Holyoke, NH – June 2012

Warwick 2012 – Warwick, England – July 2012 (Plenary)

2012 IUPAC World Polymer Congress – Blacksburg, VA – June 2012 (5 invited talks)

95th Canadian Chemistry Conference and Exhibition (CSC 2012) – May 2012

PSTC Tech 35 meeting – Boston, Massachusetts – May 2012

243rd ACS National Meeting – San Diego, California – March 2012 (2 invited talks)

APS 2012 March Meeting – Boston, Massachusetts – February/March 2012
E3 2011 – Minneapolis, Minnesota – November 2011

2011 AIChE Annual Meeting – Minneapolis, Minnesota – October 2011

Twin Cities Society of Cosmetic Chemists meeting – Roseville, MN – October 2011

242nd ACS National Meeting – Denver, Colorado – August 2011

2011 IUPAC World Chemical Congress – San Juan, Puerto Rico – August 2011

2011 IUPAC Meeting Ionic Polymerization – Akron, Ohio – July 2011

94th Canadian Chemistry Conference – Montreal, Canada – June 2011

241st ACS National Meeting – Anaheim, California – March 2011 (3 invited talks)

2011 National Australasian Polymer Symposium (Keynote) – Coffs Harbour, Australia – February 2011

2011 Macromolecular Materials Gordon Conference – Ventura, California – January 2011


2010 Materials Research Society Fall National Meeting – Boston, Massachusetts – November 2010

Int. Symposium on Nano Structured Polymeric Materials (Plenary) – Pohang, Korea – November 2010

Virginia Tech Technical Conference and Review (Plenary) – Blacksburg, Virginia – October 2010

240th ACS National Meeting – Boston, Massachusetts – August 2010

Macro 2010: 43rd IUPAC World Polymer Congress (Invited) – Glasgow, Scotland – July 2010

9th National Graduate Research Polymer Conference (Plenary) – Chapel Hill, NC – June 2010

ANTEC 2010 (Keynote) – Orlando, Florida – May 2010

239th ACS National Meeting – San Francisco, California – March 2010 (2 invited talks)

APS 2010 March Meeting – Portland, Oregon – March 2010
11th Pacific Polymer Conference (PPC11) – Cairns, Australia – December 2009

2009 Materials Research Society Fall National Meeting – Boston, Massachusetts – November 2009

2009 Minnesota Nanotechnology Conference – Minneapolis, MN – November 2009

5th Int. Conference on Materials for Advanced Technologies (ICMAT2009), Singapore – July 2009

237th ACS National Meeting – Salt Lake City, Utah – March 2009 (3 invited talks)

Zing Polymer Chemistry Conference, Playa del Carmen, Mexico – February 2009


MACRO-MEX – Los Cabos, Mexico – December 2008

International Symposium on Biological Polyesters – Auckland, New Zealand – November 2008

Innovation 2008 Conference – Minneapolis, MN – October 2008

Industrial Applications of Renewable Resources – Cincinnati, Ohio – October 2008

235th ACS National Meeting – New Orleans, Louisiana – April 2008
3rd International Conference on Nanomaterials & Nanomanufacturing – Dublin, Ireland – December 2007

2007 Minnesota Nanotechnology Conference – Minneapolis, MN – November 2007

International “Macromolecules with Designed Architectures” meeting – Sapporo, Japan – October 2007

234th ACS National Meeting – Boston, Massachusetts – August 2007

International Symposium on Metathesis XVII – Pasadena, California – July 2007

2007 High Polymer Research Group Conference – Pott Shrigley, England – April 2007


232nd ACS National Meeting – San Francisco, California – September 2006

International Symposium on Biological Polyesters – Minneapolis, Minnesota – August 2006

2006 Horizon Conference “Green Frontiers” – Cambridge, England – June 2006

Research School for Polymer Tech. RPK Short Course – Eindhoven, The Netherlands – June 2006


2005 NSF Organic Chemistry Workshop – Bodega Bay, California – July 2005

MC7: Functional Materials for the 21st Century – Edinburgh, Scotland – July 2005

AIChE Upper Midwest Section January meeting – Minneapolis, Minnesota – January 2005
Research School for Polymer Tech. RPK Short Course – Eindhoven, The Netherlands – November 2004

228th ACS National Meeting – Philadelphia, Pennsylvania – August 2004

Materials Integrity Management Symposium – Boston, Massachusetts – June 2004
Polymers for Advanced Technologies Conf. – Ft. Lauderdale, Florida – September 2003 (2 invited talks)

226th National ACS Meeting – New York, New York – September 2003

39th IUPAC Congress / 86th Canadian Soc. for Chemistry Conference – Ottawa, Canada – August 2003

IUPAC Meeting – Ionic Polymerization – Boston, Massachusetts – July 2003

Polymers East Gordon Conference – South Hadley, Massachusetts – June 2003

51st American Society of Mass Spectrometry (Keynote lecture) – Montreal, Canada – June 2003

The Midwest Organic Solid State Chemistry Symposium – Minneapolis, Minnesota – June 2003
Minnesota Section of the ACS – Bethel College – St. Paul, Minnesota – April 2003

APS 2003 March Meeting – Austin, Texas – March 2003

26th Asilomar Conference on Polymers – Pacific Grove, California – February 2003
DuPont Conference on Nanotechnology – Chesapeake Farms, Maryland – October 2002

224th National ACS Meeting – Boston, Massachusetts – August 2002 (2 invited talks)

Nanoporous Materials III – Ottawa, Ontario, Canada – June 2002
7th Pacific Polymer Conference – Oaxaca City, Mexico – December 2001

222nd National ACS Meeting – Chicago, Illinois – August 2001

ACS 33rd Central/Great Lakes Joint Regional Meeting – Grand Rapids, Michigan – June 2001

Reactive and Self–Decontaminating Surfaces Meeting – Pittsburgh, Pennsylvania – June 2001

221st National ACS Meeting – San Diego, California – March 2001
Poly Millennial 2000 Meeting – Honolulu, Hawaii – December 2000

Pacifichem 2000 Meeting – Honolulu, Hawaii – December 2000

Fluoropolymer 2000 – Savannah, Georgia – October 2000

Chemistry at Interfaces Gordon Conference – Meriden, New Hampshire – July 2000


218th National ACS Meeting – New Orleans, Louisiana – August 1999 (2 invited talks)

217th National ACS Meeting – Anaheim, California – March 1999 (2 invited talks)


ACS Rubber Division Fall Technical Meeting – Nashville, Tennessee – September 1998

Bio/Environmentally Degradable Polymer Society Meeting – Boston, Massachusetts – August 1998

Risø National Laboratory Conference on Soft Materials – Roskilde, Denmark – June 1998
Center for Polymer Interfaces and Macromolecular Assemblies – Stanford, California – August 1997

213th National ACS Meeting – San Francisco, California – April 1997


Fifth US–Germany Polymer Symposium – Leipzig, Germany – September 1996

Universities, Colleges, and Government Laboratories

Peking University Xingda Lecture – College of Chemistry and Molecular Eng. – Peking, China – January 2019


Univ. of Cal. Santa Barbara, Mellichamp Academic Initiative in Sustainability – Santa Barbara, California – May 2018

University of Waterloo, Institute for Polymer Research – Waterloo, Canada – May 2018

Tulane University, Department of Chemistry – New Orleans, Louisiana – February 2018
UC Berkeley, Department of Chemistry (Aldrich Lecture) – Berkeley, California – January 2017
St. Cloud State University Department of Chemistry – St. Cloud, Minnesota – October 2016

Penn State University, Department of Chemistry – University Park, Pennsylvania – April 2016

Notre Dame, Department of Chemistry and Biochemistry – South Bend, Indiana – April 2016

Rensselaer Polytechnic Institute, Dept. of Chemistry & Chemical Biology – Troy, New York – March 2016

UC San Diego, Department of Chemistry & Biochemistry – San Diego, California – February 2016

Miami University, Department of Chemistry and Biochemistry, Oxford, Ohio – January 2016


Washington State University, Mechanical and Materials Engineering – Pullman, Washington – November 2015

Florida State University, Department of Chemical & Biomedical Engineering – Tallahassee, Florida – October 2015

University of Indiana, Department of Chemistry – Bloomington, Indiana – September 2015

University of Akron, Dept. of Polymer Sci. (Whitby Memorial Lectureship) – Akron, Ohio – May 2015

University of Arizona, Department of Chemistry – Tucson, Arizona – April 2015

University of Utah, Department of Chemistry – Salt Lake City, Utah – March 2015

Johns Hopkins University, Dept. of Materials Sci. & Engineering – Baltimore, Maryland – February 2015

University of Minnesota, CSE Public Lecture – Minneapolis, Minnesota – January 2015


Augsburg College, Department of Chemistry, Minneapolis, Minnesota – November 2014

University of Texas, Dallas, Department of Chemistry – Dallas, Texas – October 2014

Colorado St. Univ., Dept. of Chem. (Dow Lecture in Sustainability) – Ft. Collins, Colorado – October 2014

University of Colorado, Department of Chemistry – Boulder, Colorado – October 2014

University of Victoria, Department of Chemistry – Victoria, Canada – September 2014

Simon Fraser University, Department of Chemistry – Vancouver, Canada – September 2014

Univ. of British Columbia, Dept. of Chemistry (Xerox lecture) – Vancouver, Canada – September 2014

Massachusetts Institute of Technology, Program Polym. Sci. & Tech. – Cambridge, MA – May 2014


Carnegie Mellon University, Department of Chemistry – Pittsburgh, PA – December 2013

Cornell University (Bayer Lecture), Dept. of Chemistry & Chemical Biology – Ithaca, NY – November 2013

Cornell University, Dept. of Chemistry & Chemical Biology – Ithaca, NY – November 2013

Columbia University (Aldrich Lecture), Department of Chemistry – New York, NY – October 2013

Ecole Nationale Supérieure de Chimie de Montpellier – Montpellier, France – June 2013

Université Bordeaux – LCPO – Bordeaux, France – April 2013

Université de Lyon – C2P2 & IMP – Lyon, France – April 2013
Centre de Recherche sur la Matière Divisée, CNRS – Orléans, France – November 2012

University of Texas, Department of Chemical Engineering – Austin, TX – May 2012

University of Pennsylvania, Department of Materials Science – Philadelphia, PA – April 2012

University of Washington, Department of Chemistry – Seattle, WA – April 2012

California Institute of Technology, Department of Chemistry – Pasadena, CA – March 2012

Université de Montréal, Dept. of Chem. (Grande Conférence IUPAC) – Montreal, Canada – March 2012

University of South Carolina, Department of Chemistry – Columbia, SC – February 2012

Georgia Tech, Department of Materials Science and Engineering – Atlanta, GA – January 2012


University of New Mexico, Department of Chemistry – Albuquerque, NM – May 2011

Argonne National Laboratories, Center for Nanoscale Materials – Chicago, IL – April 2011

University of California-Santa Barbara, Dept. of Materials Science – Santa Barbara, CA – April 2011

Colorado School of Mines, Department of Chemistry – Golden, CO – March 2011

University of Wisconsin, NSEC – Madison, WI – February 2011

Macalester College, Department of Chemistry – St. Paul, MN – January 2011


University of Connecticut, Institute of Materials Science – Storrs, CT – October 2010
Los Alamos National Laboratories – Los Alamos, NM – November 2009

New York University, Department of Chemistry – New York, NY – February 2009


University of Tennessee, Department of Chemistry – Knoxville, TN – September 2008

Université d'Orléans, Faculté des Sciences – Orléans, France – July 2008

Colorado State University, Departments of Chemical Eng. and Chemistry – Ft. Collins, CO – March 2008

University of Southern Mississippi, School of Polymers – Hattiesburg, MS – February 2008


University College Dublin, School of Chemistry and Chemical Biology – Dublin, Ireland – December 2007

Drexel University, Department of Chemical and Biological Engineering – Philadelphia, PA – May 2007

Massachusetts Institute of Technology, Program Polym. Sci. & Tech. – Cambridge, MA – March 2007

Gustavus Adolphus College, Department of Chemistry – St. Peter, MN – March 2007

Rensselaer Polytechnic Institute, Dept. of Chemistry and Chemical Biology – Troy, NY – February 2007

University of Wyoming, Department of Chemistry – Laramie, Wyoming – February 2007

University of Wisconsin, Department of Chemistry – Madison, Wisconsin – January 2007
University of Cambridge, Department of Chemical Engineering – Cambridge, England – July 2006

University of Reading, School of Chemistry – Reading, England – May 2006

University of Durham, Department of Chemistry – Durham, England – May 2006

University of Nottingham, School of Chemistry – Nottingham, England – March 2006

University of Sheffield, Department of Chemistry – Sheffield, England – February 2006

University of Leeds, Department of Colour and Polymer Chemistry – Leeds, England – February 2006


University of Cambridge, Department of Chemistry – Cambridge, England – December 2005

Queen Mary, University of London, Department of Physics – London, England – November 2005

University of Cambridge, Department of Physics – Cambridge, England – November 2005

Rutgers University, Department of Chemistry – Newark, New Jersey – February 2005


University of Groningen – Groningen, The Netherlands – November 2004

University of North Carolina – Chapel Hill, North Carolina – September 2004

University of Rochester – Rochester, New York – April 2004

Norfolk State University – Norfolk, Virginia – January 2004


University of Akron, Department of Polymer Science – Akron, Ohio – November 2003

Rutgers University, Department of Chemistry and Chemical Biology – Piscataway, NJ – October 2003

University of Nebraska, Department of Chemistry – Lincoln, Nebraska – October 2003

Northwestern University, MRSEC – Evanston, Illinois – April 2003

Georgia Institute of Technology, Department of Chemistry – Atlanta, Georgia – February 2003

Cornell University, Department of Materials Science – Ithaca, New York – January 2003


Massachusetts Institute of Technology, Program Polym. Sci. & Tech. – Cambridge, MA – November 2002

The Ohio State University, Department of Chemistry – Columbus, Ohio – February 2002


University of Florida, Department of Chemistry – Gainesville, Florida – November 2001

University of Wisconsin, Department of Chemical Engineering – Madison, Wisconsin – April 2001


St. Cloud State University, Department of Chemistry – St. Cloud, Minnesota – October 2000

University of Massachusetts, Department of Polymer Science – Amherst, Massachusetts – May 2000

University of Chicago, Department of Chemistry – Chicago, Illinois – April 2000

Southern Illinois University at Carbondale, Department of Chemistry – Carbondale, Illinois – March 2000


Iowa State University, Department of Chemistry – Ames, Iowa – April 1999
Gustavus Adolphus College, Department of Chemistry – Saint Peter, Minneapolis – October 1998
University of Wisconsin – Eau Claire, Dept. of Chemistry – Eau Claire, Wisconsin – November 1997
university service and committees

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