Nature Chemistry


, 1502-1512, (1999). 12 Katzin, L. I. Possible f-Shell covalency in the actinide elements. Nature 166



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121, 1502-1512, (1999).

12 Katzin, L. I. Possible f-Shell covalency in the actinide elements. Nature 166, 605-605, (1950).

13 Morss, L. R., Edelstein, N. & Fuger, J. The Chemistry of the Actinide and Transactinide Elements. 3 edn, (Springer, 2006).

14 Kozimor, S. A. et al. Trends in covalency for d- and f-element metallocene dichlorides identified using chlorine K-edge X-ray absorption spectroscopy and time-dependent density functional theory. J. Am. Chem. Soc. 131, 12125-12136, (2009).

15 Arnold, P. L. et al. Covalency in Ce(IV) and U(IV) halide and N-heterocyclic carbene bonds. Chem. Eur. J. 16, 9623-9629, (2010).

16 Diaconescu, P. L., Arnold, P. L., Baker, T. A., Mindiola, D. J. & Cummins, C. C. Arene-bridged diuranium complexes: Inverted sandwiches supported by delta backbonding. J. Am. Chem. Soc. 122, 6108-6109, (2000).

17 Diaconescu, P. L. & Cummins, C. C. μ-η66-Arene-bridged diuranium hexakisketimide complexes isolable in two states of charge. Inorg. Chem., (2012).

18 Evans, W. J., Kozimor, S. A., Ziller, J. W. & Kaltsoyannis, N. Structure, reactivity, and density functional theory analysis of the six-electron reductant, [(C5Me5)2U]2(-6:6-C6H6), synthesized via a new mode of (C5Me5)3M reactivity. J. Am. Chem. Soc. 126, 14533-14547, (2004).

19 Evans, W. J., Traina, C. A. & Ziller, J. W. Synthesis of heteroleptic uranium (6:6-C6H6)2- sandwich complexes via facile displacement of (5-C5Me5)1- by ligands of lower hapticity and their conversion to heteroleptic bis(imido) compounds. J. Am. Chem. Soc. 131, 17473-17481, (2009).

20 Monreal, M. J., Khan, S. I., Kiplinger, J. L. & Diaconescu, P. L. Molecular quadrangle formation from a diuranium -6,6-toluene complex. Chem. Commun.


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