Synthesis Of Nickel(Iı) Complexes Of Some Hydroxybenzaldehyde N-Phenyl-Thiosemicarbazones
In this study, 5-Bromosalicylaldehyde-(4-Phenyl/H)-thiosemicarbazone and 5-Bromo salicylaldehyde-S-methyl-(4-H/ Phenyl)-thiosemicarbazone ligands were synthesized. Some Ni(II) complexes (ONSP, ONNP) containing both these thioasemicarbazone derivatives (ONS and ONN) and triphenylphosphine ligand (PPh3) were obtained.
The properties and structures of ligands and their complexes were investigated by elemental analyses and spectroscopic methods (namely, IR, UV, 1H-NMR) . Single crystal structures of some Ni(II) complexes were determined by using X-Ray Diffraction Method.
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