Classification code:933.1.2 Crystal Growth - 804 Chemical Products Generally - 803 Chemical Agents and Basic Industrial Chemicals - 802.3 Chemical Operations - 802.2 Chemical Reactions - 761 Nanotechnology - 711.1 Electromagnetic Waves in Different Media - 547.2 Rare Earth Metals - 536 Powder Metallurgy
DOI:10.1016/j.matlet.2010.10.013
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20105013484831
Title:Study on adsorption and desorption properties of the starch grafted p-tert-butyl-calix[n]arene for butyl Rhodamine B solution
Authors:Chen, Ming (1); Shang, Ting (1); Fang, Wei (1); Diao, Guowang (1)
Author affiliation:(1) College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China; (2) Key Laboratory of Environmental Materials, Environmental Engineering of Jiangsu Province, Yangzhou, Jiangsu, 225002, China
Corresponding author:Diao, G.(gwdiao@yzu.edu.cn)
Source title:Journal of Hazardous Materials
Abbreviated source title:J. Hazard. Mater.
Volume:185
Issue:2-3
Issue date:January 30, 2011
Publication year:2011
Pages:914-921
Language:English
ISSN:03043894
CODEN:JHMAD9
Document type:Journal article (JA)
Publisher:Elsevier, P.O. Box 211, Amsterdam, 1000 AE, Netherlands
Abstract:The adsorbents of starch grafted p-tert-butyl-calix[4,6,8]arene-SGCn (SGC4, SGC6, SGC8) are prepared. The products are characterized by FTIR, elemental analysis, thermal gravimetric analysis and scanning electron microscope. Static adsorption behavior is studied by using SGC8 as adsorbent, butyl Rhodamine B (BRB) solution as simulation dye wastewater. The adsorption of BRB onto SGC8 fits the second order kinetic model and the apparent adsorption rate constant is 0.002gmg-1min-1 at 25°C. The equilibrium adsorption data are interpreted using Langmuir and Freundlich models. The adsorption of BRB onto SGC8 is better represented by the Langmuir equation. The thermodynamic parameters for the adsorption reaction are calculated through van't Hoff analysis. The adsorbent may be easily regenerated by using ethanol solution as desorption agent to extract dye from SGC8. The rate of desorption of BRB is dependent on the concentration of ethanol and the temperature. SGC8 exhibits excellent adsorption and desorption properties toward dye molecule. The new-style adsorbent of SGC8 is regarded as a potential adsorbent to deal with dye or organic wastewater. © 2010 Elsevier B.V.
Number of references:56
Main heading:Adsorption
Controlled terms:Adsorbents - Adsorption isotherms - Desorption - Ethanol - Grafting (chemical) - Rate constants - Scanning electron microscopy - Starch - Thermogravimetric analysis - Wastewater
Uncontrolled terms:Adsorption reaction - Apparent adsorption - Desorption properties - Dye molecule - Dye wastewaters - Elemental analysis - Equilibrium adsorption - Ethanol solutions - Freundlich models - FTIR - Langmuir equation - Langmuirs - Organic wastewater - P-Tert-butyl-calix[4,6,8]arene - Potential adsorbents - Rhodamine B - Scanning Electron Microscope - Second order kinetics - Static adsorption - Thermal gravimetric analysis - Thermodynamic parameter - Van't Hoff Analysis
Classification code:804.1 Organic Compounds - 803 Chemical Agents and Basic Industrial Chemicals - 802.3 Chemical Operations - 802.2 Chemical Reactions - 801.4 Physical Chemistry - 801 Chemistry - 741.1 Light/Optics - 523 Liquid Fuels - 452.3 Industrial Wastes
DOI:10.1016/j.jhazmat.2010.09.107
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20104413347529
Title:Synthesis of Na-doped ZnO nanowires and their antibacterial properties
Authors:Wu, Changle (1); Shen, Li (2); Huang, Qingli (1); Zhang, Yong-Cai (2)
Author affiliation:(1) Testing Center of Yangzhou University, Yangzhou 225009, Jiangsu, China; (2) College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Corresponding author:Wu, C.(clwu@yzu.edu.cn)
Source title:Powder Technology
Abbreviated source title:Powder Technol.
Volume:205
Issue:1-3
Issue date:January 10, 2011
Publication year:2011
Pages:137-142
Language:English
ISSN:00325910
CODEN:POTEBX
Document type:Journal article (JA)
Publisher:Elsevier, P.O. Box 211, Amsterdam, 1000 AE, Netherlands
Abstract:Na-doped ZnO nanowires with an average diameter of ~. 40. nm have been fabricated by a thermal decomposition route at temperatures around 400°C. Their properties have been investigated using X-ray diffraction, field emission scanning electron microscope, Raman spectra, photoluminescence spectra and X-ray photoelectron spectra. Photoluminescence spectra showed that the as-synthesized ZnO samples exhibited strong visible emission with a major peak at 420. nm. Furthermore, intensity of the visible emission at 420. nm enhanced as the increase of Na concentration. The improvement of visible emission in the Na-doped ZnO samples should be a result of the surface defects increased by doping of Na in ZnO. Their antibacterial activities were also evaluated by determination of minimum inhibitory concentration (MIC) against Escherichia coli 25922 in vitro. Antibacterial tests indicated these nanomaterials showed good antibacterial properties after UV illumination for a short time. © 2010 Elsevier B.V.
Number of references:42
Main heading:Zinc oxide
Controlled terms:Doping (additives) - Escherichia coli - Field emission - Nanowires - Photoluminescence - Pyrolysis - Raman spectroscopy - Scanning electron microscopy - Sodium - Surface defects - Synthesis (chemical) - X ray diffraction - X ray diffraction analysis - X ray photoelectron spectroscopy
Uncontrolled terms:A-thermal - Anti-bacterial activity - Antibacterial properties - Antibacterial tests - Average diameter - Chemical synthesis - Field emission scanning electron microscopes - In-vitro - Minimum inhibitory concentration - Na concentration - Na-Doped ZnO - Nano-materials - Photoluminescence spectrum - Raman spectra - UV illuminations - Visible emissions - X ray photoelectron spectra - ZnO
Classification code:933.1.1 Crystal Lattice - 933 Solid State Physics - 932 High Energy Physics; Nuclear Physics; Plasma Physics - 804.2 Inorganic Compounds - 802.2 Chemical Reactions - 951 Materials Science - 801.2 Biochemistry - 761 Nanotechnology - 741.1 Light/Optics - 549.1 Alkali Metals - 421 Strength of Building Materials; Mechanical Properties - 801 Chemistry
DOI:10.1016/j.powtec.2010.09.003
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20105013484731
Title:Equilibration in a geranyl acetate emulsion
Authors:Bozeya, Ayat (1); Al-Bawab, Abeer (2); Friberg, Stig E. (3); Guo, Rong (3)
Author affiliation:(1) Hamdi Mango Center for Scientific Research (HMCSR), University of Jordan, Amman, Jordan; (2) Chemistry Department, University of Jordan, PO Box 13536, Amman 11942, Jordan; (3) School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, China
Corresponding author:Al-Bawab, A.(drabeer@ju.edu.jo)
Source title:Colloids and Surfaces A: Physicochemical and Engineering Aspects
Abbreviated source title:Colloids Surf. A Physicochem. Eng. Asp.
Volume:373
Issue:1-3
Issue date:January 3, 2011
Publication year:2011
Pages:110-115
Language:English
ISSN:09277757
CODEN:CPEAEH
Document type:Journal article (JA)
Publisher:Elsevier, P.O. Box 211, Amsterdam, 1000 AE, Netherlands
Abstract:Water and a geranyl acetate solution of a non-ionic surfactant, a commercial C12EO4, were brought into contact in amounts to give a combination of a lamellar liquid crystal and an oil phase of equal weights at equilibrium and the equilibration transport between the layers was followed by measuring the change in layer heights with time. The initial reaction, lasting approximately two months, transferred surfactant from the oil phase to combine with water to form a birefringent layer initially containing excess water over the fraction in the liquid crystal in equilibrium with both water and oil phase. After this period the composition of the oil phase had reached a level corresponding to equilibrium with both water and a lamellar liquid crystal, while the birefringent phase, although a liquid crystal, still contained less water fraction than required for equilibrium. The final equilibration process of transferring the excess water to the formed liquid crystal was extremely slow with an estimated time to reach equilibrium of several years. © 2010 Elsevier B.V.
Number of references:68
Main heading:Liquid crystals
Controlled terms:Birefringence - Emulsification - Surface active agents
Uncontrolled terms:Birefringent layers - Equilibration - Equilibration process - Geranyl acetate - Lamellar liquid crystal - Oil phase - Water fraction
Classification code:741.1 Light/Optics - 802.3 Chemical Operations - 803 Chemical Agents and Basic Industrial Chemicals - 804 Chemical Products Generally
DOI:10.1016/j.colsurfa.2010.10.037
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20105013480941
Title:Preparation of SnS2 thin films by chemical bath deposition
Authors:Li, Jing (1); Zhang, Yong Cai (1); Zhang, Ming (1)
Author affiliation:(1) Key Laboratory of Environmental Material and Environmental Engineering of Jiangsu Province, College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
Corresponding author:Zhang, Y. C.(zhangyc@yzu.edu.cn)
Source title:Materials Science Forum
Abbreviated source title:Mater. Sci. Forum
Volume:663-665
Monograph title:Optoelectronic Materials
Issue date:2011
Publication year:2011
Pages:104-107
Language:English
ISSN:02555476
CODEN:MSFOEP
ISBN-10:0878492119
ISBN-13:9780878492114
Document type:Conference article (CA)
Conference name:2010 International Conference on Optical, Electronic and Electrical Materials, OEEM2010
Conference date:August 1, 2010 - August 4, 2010
Conference location:Kunming, China
Conference code:82669
Sponsor:National Science Foundation of China; Trans Tech Publications
Publisher:Trans Tech Publications Ltd, Laubisrutistr.24, Stafa-Zuerich, CH-8712, Switzerland
Abstract:A chemical bath deposition method has been proposed for the preparation of SnS2 thin films onto glass slides from the aqueous solutions of tin (IV) chloride pentahydrate, thioacetamide and citric acid at 35°C. High quality SnS2 thin films were obtained by adjusting the amounts of citric acid, which was used here as a complexing agent. The as-prepared thin films were characterized by Raman spectra, field emission scanning electron microscopy (FESEM), surface profiler and UV-vis absorption spectra. Raman spectra revealed that the as-prepared films were of hexagonal phase SnS2. FESEM images and surface profiler measurements indicated that the SnS2 thin film deposited under the optimum condition was homogeneous and well adhered to the substrate, with a thickness of about 200 nm. Optical absorption measurements disclosed that the SnS2 thin film deposited under the optimum condition had a band gap of about 2.40 eV. © (2011) Trans Tech Publications.
Number of references:10
Main heading:Optical films
Controlled terms:Absorption - Chlorine compounds - Citric acid - Deposition - Field emission - Field emission microscopes - Film preparation - Film thickness - Light absorption - Optical properties - Optoelectronic devices - Raman scattering - Raman spectroscopy - Scanning electron microscopy - Thin films - Tin - Ultraviolet spectroscopy - Vapor deposition
Uncontrolled terms:Aqueous solutions - Band gaps - Chemical bath deposition methods - Chemical-bath deposition - Complexing agents - Field emission scanning electron microscopy - Glass slides - Hexagonal phase - High quality - Optical absorption measurement - Optimum conditions - Raman spectra - Surface profilers - Thioacetamide - Tin chlorides - UV-VIS absorption spectra
Classification code:943 Mechanical and Miscellaneous Measuring Instruments - 931.2 Physical Properties of Gases, Liquids and Solids - 822 Food Technology - 813.1 Coating Techniques - 804.1 Organic Compounds - 802.2 Chemical Reactions - 801 Chemistry - 741.3 Optical Devices and Systems - 741.1 Light/Optics - 714.2 Semiconductor Devices and Integrated Circuits - 712.1 Semiconducting Materials - 546.2 Tin and Alloys - 423 Non Mechanical Properties and Tests of Building Materials
DOI:10.4028/www.scientific.net/MSF.663-665.104
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20110713667741
Title:Determination of Nickel(II) by CTAB sensitized fluorescence quenching method of the derivatives of calix[4]arene
Authors:Zhu, Xiashi (1); Ma, Lina (1)
Author affiliation:(1) Department of Chemistry, Yangzhou University, Yangzhou 225002, China
Corresponding author:Zhu, X.(xszhu@yzu.edu.cn)
Source title:Journal of Fluorescence
Abbreviated source title:J Fluoresc
Volume:21
Issue:1
Issue date:January 2011
Publication year:2011
Pages:321-326
Language:English
ISSN:10530509
CODEN:JOFLEN
Document type:Journal article (JA)
Publisher:Springer New York, 233 Springer Street, New York, NY 10013-1578, United States
Abstract:The fluorescence quenching effect of Ni2+ on the derivatives of p-tert- butyl-calix[4]arene with o-phenanthroline(TBCP) was studied in cetyltrimethyl- ammonium bromide (CTAB) medium. Ni2+ reacted with the TBCP to form inclusion complex. The fluorescence quenching was sensitized in CTAB. The linear range of calibration curve for the determination of Ni 2+ was 0.050 μg/mL ~ 1.00 μg/mL. The detection limit estimated (S/N∈=∈3) was 5.3 ng/mL. It has been applied for the determination of Ni(II) in samples with satisfactory results. © 2010 Springer Science+Business Media, LLC.
Number of references:22
Main heading:Fluorescence
Controlled terms:Ammonium compounds - Bromine compounds - Nickel compounds - Quenching
Uncontrolled terms:Calix[4]arenes - CTAB - Fluorescence quenching - Ni(II) - Sensitized
Classification code:537.1 Heat Treatment Processes - 741.1 Light/Optics - 804.1 Organic Compounds
DOI:10.1007/s10895-010-0719-9
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20110513634688
Title:Sodium dodecyl sulfate sensitized electrochemical method for sub-picomole level determination of topotecan hydrochloride at a novel disposable electrode
Authors:Li, Hongbo (1); Li, Jing (2); Yang, Zhanjun (1); Xu, Qin (1); Hu, Xiaoya (1)
Author affiliation:(1) College of Chemistry and Engineering, Yangzhou University, Yangzhou 225002, China; (2) Chemistry and Biology Engineering School, Yancheng Institute of Technology, Yancheng 224051, China
Corresponding author:Hu, X.(xyhu@yzu.edu.cn)
Source title:Science China Chemistry
Abbreviated source title:Sci. China Chem.
Volume:54
Issue:1
Issue date:January 2011
Publication year:2011
Pages:217-222
Language:English
ISSN:16747291
CODEN:SCCCCS
Document type:Conference article (CA)
Publisher:Science in China Press, 16 Donghuangchenggen North Street, Beijing, PR 100717, China
Abstract:A sub-picomole level topotecan hydrochloride determination method was first proposed using sodium dodecyl sulfate (SDS) as a sensitized reagent at a novel disposable electrode (an improved wax-impregnated graphite electrode). The effects of different kinds of surfactants on the electrochemical response to topotecan hydrochloride were examined. The results indicate the electrochemical signal was apparently improved by SDS. At optimal conditions, the oxidative peak current increased linearly with the logarithm of concentrations for topotecan hydrochloride in the ranges of 2.0 × 10-12 to 1.0 × 10-11 mol/L and 8.0 × 10-11 to 8.0 × 10 -10 mol/L with a detection limit of 6.4 × 10-13 mol/L. The proposed method could be applied in determining topotecan hydrochloride in urine. © 2010 Science China Press and Springer-Verlag Berlin Heidelberg.
Number of references:35
Main heading:Electrochemical electrodes
Controlled terms:Algebra - Graphite electrodes - Sodium - Sodium sulfate - Surface active agents
Uncontrolled terms:Detection limits - Determination methods - Disposable electrodes - electroanalysis - ELectrochemical methods - Electrochemical response - Electrochemical signals - Optimal conditions - Peak currents - Sodium dodecyl sulfate - sodium dodecyl sulfate (SDS) - Topotecan
Classification code:549.1 Alkali Metals - 704.1 Electric Components - 804.2 Inorganic Compounds - 921.1 Algebra
DOI:10.1007/s11426-010-4089-6
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20104013273634
Title:Complexation thermodynamics between butyl rhodamine B and calix[n]arenesulfonates (n = 4, 6, 8)
Authors:Chen, Ming (0); Shang, Ting (0); Liu, Jie (0); Diao, Guowang (0)
Corresponding author:Diao, G.(gwdiao@yzu.edu.cn)
Corr. author affiliation:College of Chemistry and Chemical Engineering; Yangzhou University, Yangzhou 225002, China
Source title:Journal of Chemical Thermodynamics
Abbreviated source title:J Chem Thermodyn
Volume:43
Issue:1
Issue date:January 2011
Publication year:2011
Pages:88-93
Language:English
ISSN:00219614
E-ISSN:10963626
CODEN:JCTDAF
Document type:Journal article (JA)
Publisher:Academic Press, 24-28 Oval Road, London, NW1 7DX, United Kingdom
Abstract:The characteristics of host-guest complexation between water-soluble calix[n]arenesulfonates (CnS, n = 4, 6, 8) and butyl rhodamine B (BRB) were investigated by fluorescence spectrometry. Fluorescence spectroscopy experiments were performed in pH 8.0 Tris(3-aminomethane)-HCl buffer solution at different temperature to calculate the stability constants (KS) for the stoichiometric 1:1 inclusion complexes of C4S, C6S, and C8S with BRB. The complex stability constant monotonically increased with the number of phenolic units in the calixarene ring. The thermodynamic parameters at T = 298 K for the inclusion complexes were calculated through Van't Hoff analysis. The inclusion complexes of CnS with BRB were driven by the favorable enthalpic changes, accompanying negative entropy changes. The stability constants were affected by the acidity of the solution. When pH was 8.0, the stability constants reached the maximum. The complex interaction was mainly attributed to the weak forces including electrostatic interaction and hydrogen bonding. © 2010 Elsevier Ltd. All rights reserved.
Number of references:19
Main heading:Complexation
Controlled terms:Dyes - Fluorescence - Fluorescence spectroscopy - Hydrochloric acid - Hydrogen bonds - Phenols - Stability - Thermodynamics
Uncontrolled terms:Arenesulfonates - Inclusion complex - Rhodamine B - Stability constant - Thermodynamics parameter
Classification code:961 Systems Science - 951 Materials Science - 931 Classical Physics; Quantum Theory; Relativity - 804.1 Organic Compounds - 803 Chemical Agents and Basic Industrial Chemicals - 802.2 Chemical Reactions - 801.4 Physical Chemistry - 801 Chemistry - 741.3 Optical Devices and Systems - 741.1 Light/Optics - 641.1 Thermodynamics
DOI:10.1016/j.jct.2010.08.014
Database:Compendex
Compilation and indexing terms, Copyright 2011 Elsevier Inc.
Accession number:20110213577716
Title:Genetic analysis of starch paste viscosity parameters in glutinous rice (Oryza sativa L.)
Authors:Yan, Chang-Jie (1); Tian, Zhi-Xi (2); Fang, Yu-Wei (1); Yang, Ya-Chun (1); Li, Jian (1); Zeng, Sheng-Yuan (1); Gu, Shi-Liang (1); Xu, Chen-Wu (1); Tang, Shu-Zhu (1); Gu, Ming-Hong (1)
Author affiliation:(1) Jiangsu Key Laboratory of Crop Genetics and Physiology, Key Laboratory of Plant Functional Genomics, Ministry of Education of China, Agricultural College of Yangzhou University, 12 East Wenhui Road, Jiangsu 225009, China; (2) Institute of Genetics and Developmental Biology, Chinese Academy of Science, Beijing 100101, China
Corresponding author:Gu, M.-H.(gumh@yzu.edu.cn)
Source title:Theoretical and Applied Genetics
Abbreviated source title:Theor. Appl. Genet.
Volume:122
Issue:1
Issue date:2011
Publication year:2011
Pages:63-76
Language:English
ISSN:00405752
CODEN:THAGA6
Document type:Journal article (JA)
Publisher:Springer Verlag, Tiergartenstrasse 17, Heidelberg, D-69121, Germany
Abstract:Starch paste viscosity plays an important role in estimating the cooking, eating, and processing quality of rice. The inheritance of starch paste viscosity in glutinous rice remains undefined. In the present study, 118 glutinous rice accessions were collected, and the genotypes of 17 starch synthesis-related genes (SSRG) were analyzed by using 43 gene-specific molecular markers. Association analysis indicated that 10 of 17 SSRGs were involved in controlling the rapid visco analyzer (RVA) profile parameters. Among these, the PUL gene was identified to play an important role in control of peak viscosity (PKV), hot paste viscosity (HPV), cool paste viscosity (CPV), breakdown viscosity (BDV), peak time (PeT), and paste temperature (PaT) in glutinous rice. Other SSRGs involved only a few RVA profile parameters. Furthermore, interactions between SSRGs were found being responsible for PeT, PaT, and BDV. Some of the RVA parameters, including PKV, HPV, CPV, CSV, and PaT, were mainly governed by single SSRG, whereas other parameters, such as BDV, SBV, and PeT, were controlled by a few SSRGs, functioning cooperatively. Further, three near-isogenic lines (NIL) of a japonica glutinous cv. Suyunuo as genetic background, with PUL, SSIII-1, and SSIII-2 alleles replaced with those of indica cv. Guichao 2, were employed to verify the genetic effects of the various genes, and the results were consistent with those obtained from the association analysis. These findings indicated that starch paste viscosity in glutinous rice had a complex genetic system, and the PUL gene played an important role in determining the RVA profile parameters in glutinous rice. These results provide important information for potentially improving the quality of glutinous rice. © 2010 Springer-Verlag.
Number of references:49
Main heading:Parameter estimation
Controlled terms:Genes - Starch - Viscosity
Uncontrolled terms:Association analysis - Breakdown viscosity - Genetic analysis - Genetic backgrounds - Genetic effects - Genetic systems - Glutinous rice - In-control - Molecular marker - Near-isogenic lines - Oryza sativa - Paste viscosity - Peak viscosities - Processing quality - Profile parameters - Rapid visco analyzers - Starch pastes - Starch synthesis - Starch synthesis related genes
Dostları ilə paylaş: |